Vibrational spectra of bridging carbonyl groups in transition metal carbonyl clusters

S. F.A. Kettle, E. Boccaleri, E. Diana, M. C. Iapalucci, R. Rossetti, Pier Luigi Stanghellini

Risultato della ricerca: Contributo su rivistaArticolo in rivistapeer review

Abstract

The spherical harmonic model (SHM), previously used for the analysis of the terminal ν(CO) vibrations of transition metal carbonyl clusters, is applied to the corresponding bridging CO modes. The model is applicable, although the spectra show a greater sensitivity to the molecular geometry than is the case for their terminal counterparts. The reasons for this sensitivity are discussed. When both μ2 and μ3 CO groups are present in a molecule, a spectral distinction may not be apparent.

Lingua originaleInglese
pagine (da-a)3620-3627
Numero di pagine8
RivistaInorganic Chemistry
Volume41
Numero di pubblicazione14
DOI
Stato di pubblicazionePubblicato - 15 lug 2002

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