Two-dimensional non-close-packed arrays of nanoparticles via core-shell nanospheres and reactive ion etching

Katia Sparnacci, Diego Antonioli, Simone Deregibus, Guido Panzarasa, Michele Laus, Natascia de Leo, Luca Boarino, Valerj Kapeliouchko, Tiziana Poggio

Risultato della ricerca: Contributo su rivistaArticolo in rivistapeer review

Abstract

Nanosized PTFE/polystyrene core-shell particles were prepared by seed emulsion polymerization technique starting from PTFE seeds of 20nm. At the end of the reaction, no residual PTFE nor secondary nucleation was observed and by appropriately choosing the ratio between the monomer and the PTFE seed it was possible to obtain particles, with predetermined size in the range 60-100nm, featuring an extremely narrow size distribution. These particles were successfully employed as building blocks for the preparation of large scale nanosized monolayers through the floating technique. Reactive ion etching was further applied to modulate the size characteristics of the resulting 2D ordered nanostructure. Although for relatively short RIE times a peculiar continuous morphology was observed in which the particles are interconnected through thin arms, on further increasing the RIE time a well-organized 2D arrangement of particles with size of about 30nm was obtained. Considering the shell as an expendable ordering and spacing tool, the use of core-shell nanospheres allows a wide variety of controlled morphologies to be designed and prepared thus opening new perspectives for nanostructure fabrication processes through nanosphere lithography (NSL).

Lingua originaleInglese
pagine (da-a)558-564
Numero di pagine7
RivistaPolymers for Advanced Technologies
Volume23
Numero di pubblicazione3
DOI
Stato di pubblicazionePubblicato - mar 2012

Fingerprint

Entra nei temi di ricerca di 'Two-dimensional non-close-packed arrays of nanoparticles via core-shell nanospheres and reactive ion etching'. Insieme formano una fingerprint unica.

Cita questo