The Water-Exchange Rate in Neutral Heptadentate DO3A-Like GdIII Complexes: Effect of the Basicity at the Macrocyclic Nitrogen Site

Enzo Terreno; Patrizia Boniforte; Mauro Botta; Franco Fedeli; Luciano Milone; Armando Mortillaro; Silvio Aime

doi:10.1002/ejic.200300356

The Water-Exchange Rate in Neutral Heptadentate DO3A-Like Gd^III Complexes: Effect of the Basicity at the Macrocyclic Nitrogen Site

Enzo Terreno
, Patrizia Boniforte
, Mauro Botta
, Franco Fedeli
, Luciano Milone
, Armando Mortillaro
, Silvio Aime

Dipartimento di Scienze e Innovazione Tecnologica

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

The rate of exchange of the two water molecules coordinated to a Gd ^III centre in neutral complexes with heptadentate DO3A derivatives is modulated by the basicity of the macrocyclic nitrogen bearing the pendant group: a lower basicity results in a slower water-exchange rate.

Lingua originale	Inglese
pagine (da-a)	3530-3533
Numero di pagine	4
Rivista	European Journal of Inorganic Chemistry
Numero di pubblicazione	19
DOI	https://doi.org/10.1002/ejic.200300356
Stato di pubblicazione	Pubblicato - 6 ott 2003

Accesso al documento

10.1002/ejic.200300356

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title = "The Water-Exchange Rate in Neutral Heptadentate DO3A-Like GdIII Complexes: Effect of the Basicity at the Macrocyclic Nitrogen Site",

abstract = "The rate of exchange of the two water molecules coordinated to a Gd III centre in neutral complexes with heptadentate DO3A derivatives is modulated by the basicity of the macrocyclic nitrogen bearing the pendant group: a lower basicity results in a slower water-exchange rate.",

keywords = "Gadolinium, Imaging agents, Kinetics, Water exchange",

author = "Enzo Terreno and Patrizia Boniforte and Mauro Botta and Franco Fedeli and Luciano Milone and Armando Mortillaro and Silvio Aime",

year = "2003",

month = oct,

day = "6",

doi = "10.1002/ejic.200300356",

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journal = "European Journal of Inorganic Chemistry",

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T2 - Effect of the Basicity at the Macrocyclic Nitrogen Site

AU - Terreno, Enzo

AU - Boniforte, Patrizia

AU - Botta, Mauro

AU - Fedeli, Franco

AU - Milone, Luciano

AU - Mortillaro, Armando

AU - Aime, Silvio

PY - 2003/10/6

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AB - The rate of exchange of the two water molecules coordinated to a Gd III centre in neutral complexes with heptadentate DO3A derivatives is modulated by the basicity of the macrocyclic nitrogen bearing the pendant group: a lower basicity results in a slower water-exchange rate.

KW - Gadolinium

KW - Imaging agents

KW - Kinetics

KW - Water exchange

UR - https://www.scopus.com/pages/publications/0142152520

U2 - 10.1002/ejic.200300356

DO - 10.1002/ejic.200300356

M3 - Article

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JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

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