The Water-Exchange Rate in Neutral Heptadentate DO3A-Like GdIII Complexes: Effect of the Basicity at the Macrocyclic Nitrogen Site

Enzo Terreno, Patrizia Boniforte, Mauro Botta, Franco Fedeli, Luciano Milone, Armando Mortillaro, Silvio Aime

Risultato della ricerca: Contributo su rivistaArticolo in rivistapeer review

Abstract

The rate of exchange of the two water molecules coordinated to a Gd III centre in neutral complexes with heptadentate DO3A derivatives is modulated by the basicity of the macrocyclic nitrogen bearing the pendant group: a lower basicity results in a slower water-exchange rate.

Lingua originaleInglese
pagine (da-a)3530-3533
Numero di pagine4
RivistaEuropean Journal of Inorganic Chemistry
Numero di pubblicazione19
DOI
Stato di pubblicazionePubblicato - 6 ott 2003

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