The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metals carbonyl cluster compounds Part 2. Some M5 species

S. F.A. Kettle; E. Diana; P. L. Stanghellini; R. Della Pergola; A. Fumagalli

doi:10.1016/0020-1693(95)90083-I

The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metals carbonyl cluster compounds Part 2. Some M₅ species

S. F.A. Kettle, E. Diana, P. L. Stanghellini, R. Della Pergola, A. Fumagalli

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

A study of the ν(CO) spectra of six M₅ trigonal bipyramidal cluster carbonyls shows that the patterns observed are consistent with the postulate that the bridgingspectra are more structure-sensitive than are the terminal ones. A qualitative suggestion is made concerning predictions for species with bridge CO groups with significantly different ν(CO) zeroth-order frequency differences.

Lingua originale	Inglese
pagine (da-a)	407-411
Numero di pagine	5
Rivista	Inorganica Chimica Acta
Volume	235
Numero di pubblicazione	1-2
DOI	https://doi.org/10.1016/0020-1693(95)90083-I
Stato di pubblicazione	Pubblicato - lug 1995
Pubblicato esternamente	Sì

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10.1016/0020-1693(95)90083-I

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Kettle, S. F. A., Diana, E., Stanghellini, P. L., Della Pergola, R., & Fumagalli, A. (1995). The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metals carbonyl cluster compounds Part 2. Some M₅ species. Inorganica Chimica Acta, 235(1-2), 407-411. https://doi.org/10.1016/0020-1693(95)90083-I

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title = "The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metals carbonyl cluster compounds Part 2. Some M5 species",

abstract = "A study of the ν(CO) spectra of six M5 trigonal bipyramidal cluster carbonyls shows that the patterns observed are consistent with the postulate that the bridgingspectra are more structure-sensitive than are the terminal ones. A qualitative suggestion is made concerning predictions for species with bridge CO groups with significantly different ν(CO) zeroth-order frequency differences.",

keywords = "Carbonyl complexes, Cluster complexes, Infrared Raman spectroscopy, Transition metal complexes",

author = "Kettle, {S. F.A.} and E. Diana and Stanghellini, {P. L.} and {Della Pergola}, R. and A. Fumagalli",

note = "Funding Information: We are indebtedt o Dr E. Agosti (Dipartimentod i ChimicaI ndustriale,P olitecnicod i Milano) for technical assistancwe ith the measuremenotsf the Raman spectra. Financial support from the Italian CNR (Progettob i-lateraled i ricercaf or P.L.S. and S.F.A.K.) is gratefully acknowledged.",

year = "1995",

month = jul,

doi = "10.1016/0020-1693(95)90083-I",

language = "English",

volume = "235",

pages = "407--411",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

number = "1-2",

}

Kettle, SFA, Diana, E, Stanghellini, PL, Della Pergola, R & Fumagalli, A 1995, 'The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metals carbonyl cluster compounds Part 2. Some M₅ species', Inorganica Chimica Acta, vol. 235, n. 1-2, pagg. 407-411. https://doi.org/10.1016/0020-1693(95)90083-I

The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metals carbonyl cluster compounds Part 2. Some M₅ species. / Kettle, S. F.A.; Diana, E.; Stanghellini, P. L. et al.
In: Inorganica Chimica Acta, Vol. 235, N. 1-2, 07.1995, pag. 407-411.

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

TY - JOUR

T1 - The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metals carbonyl cluster compounds Part 2. Some M5 species

AU - Kettle, S. F.A.

AU - Diana, E.

AU - Stanghellini, P. L.

AU - Della Pergola, R.

AU - Fumagalli, A.

N1 - Funding Information: We are indebtedt o Dr E. Agosti (Dipartimentod i ChimicaI ndustriale,P olitecnicod i Milano) for technical assistancwe ith the measuremenotsf the Raman spectra. Financial support from the Italian CNR (Progettob i-lateraled i ricercaf or P.L.S. and S.F.A.K.) is gratefully acknowledged.

PY - 1995/7

Y1 - 1995/7

N2 - A study of the ν(CO) spectra of six M5 trigonal bipyramidal cluster carbonyls shows that the patterns observed are consistent with the postulate that the bridgingspectra are more structure-sensitive than are the terminal ones. A qualitative suggestion is made concerning predictions for species with bridge CO groups with significantly different ν(CO) zeroth-order frequency differences.

AB - A study of the ν(CO) spectra of six M5 trigonal bipyramidal cluster carbonyls shows that the patterns observed are consistent with the postulate that the bridgingspectra are more structure-sensitive than are the terminal ones. A qualitative suggestion is made concerning predictions for species with bridge CO groups with significantly different ν(CO) zeroth-order frequency differences.

KW - Carbonyl complexes

KW - Cluster complexes

KW - Infrared Raman spectroscopy

KW - Transition metal complexes

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U2 - 10.1016/0020-1693(95)90083-I

DO - 10.1016/0020-1693(95)90083-I

M3 - Article

SN - 0020-1693

VL - 235

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JO - Inorganica Chimica Acta

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