The structures and fluxional behaviour of the binary carbonyls; A new approach. Part 3. The fluxional behaviour of [fe3(CO)11L], L = PR3 or P(OR)3

Robert E. Benfield; Paul D. Gavens; Brian F.G. Johnson; Martin J. Mays; Silvo Aime; Luciano Milone; Domenico Osella

doi:10.1039/DT9810001535

The structures and fluxional behaviour of the binary carbonyls; A new approach. Part 3. The fluxional behaviour of [fe₃(CO)₁₁L], L = PR₃ or P(OR)₃

Robert E. Benfield, Paul D. Gavens, Brian F.G. Johnson, Martin J. Mays, Silvo Aime, Luciano Milone, Domenico Osella

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

The stereodynamic behaviour of the complexes [Fe₃(CO)₁₁L] [L = PR₃ or P(OR)₃], as determined by ¹³C n.m.r. spectroscopy over a wide temperature range, has been interpreted in terms of an icosahedral ⇌ cube-octahedral interchange of ligands of the type previously postulated for [M₄(CO)₁₂] (M = Co, Rh, or lr) and their derivatives.

Lingua originale	Inglese
pagine (da-a)	1535-1539
Numero di pagine	5
Rivista	Journal of the Chemical Society. Dalton Transactions
Numero di pubblicazione	7
DOI	https://doi.org/10.1039/DT9810001535
Stato di pubblicazione	Pubblicato - 1981
Pubblicato esternamente	Sì

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10.1039/DT9810001535

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title = "The structures and fluxional behaviour of the binary carbonyls; A new approach. Part 3. The fluxional behaviour of [fe3(CO)11L], L = PR3 or P(OR)3",

abstract = "The stereodynamic behaviour of the complexes [Fe3(CO)11L] [L = PR3 or P(OR)3], as determined by 13C n.m.r. spectroscopy over a wide temperature range, has been interpreted in terms of an icosahedral ⇌ cube-octahedral interchange of ligands of the type previously postulated for [M4(CO)12] (M = Co, Rh, or lr) and their derivatives.",

author = "Benfield, {Robert E.} and Gavens, {Paul D.} and Johnson, {Brian F.G.} and Mays, {Martin J.} and Silvo Aime and Luciano Milone and Domenico Osella",

year = "1981",

doi = "10.1039/DT9810001535",

language = "English",

pages = "1535--1539",

journal = "Journal of the Chemical Society. Dalton Transactions",

issn = "1472-7773",

publisher = "Royal Society of Chemistry",

number = "7",

}

The structures and fluxional behaviour of the binary carbonyls; A new approach. Part 3. The fluxional behaviour of [fe₃(CO)₁₁L], L = PR₃ or P(OR)₃. / Benfield, Robert E.; Gavens, Paul D.; Johnson, Brian F.G. et al.
In: Journal of the Chemical Society. Dalton Transactions, N. 7, 1981, pag. 1535-1539.

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

TY - JOUR

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AU - Benfield, Robert E.

AU - Gavens, Paul D.

AU - Johnson, Brian F.G.

AU - Mays, Martin J.

AU - Aime, Silvo

AU - Milone, Luciano

AU - Osella, Domenico

PY - 1981

Y1 - 1981

N2 - The stereodynamic behaviour of the complexes [Fe3(CO)11L] [L = PR3 or P(OR)3], as determined by 13C n.m.r. spectroscopy over a wide temperature range, has been interpreted in terms of an icosahedral ⇌ cube-octahedral interchange of ligands of the type previously postulated for [M4(CO)12] (M = Co, Rh, or lr) and their derivatives.

AB - The stereodynamic behaviour of the complexes [Fe3(CO)11L] [L = PR3 or P(OR)3], as determined by 13C n.m.r. spectroscopy over a wide temperature range, has been interpreted in terms of an icosahedral ⇌ cube-octahedral interchange of ligands of the type previously postulated for [M4(CO)12] (M = Co, Rh, or lr) and their derivatives.

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U2 - 10.1039/DT9810001535

DO - 10.1039/DT9810001535

M3 - Article

SN - 1472-7773

SP - 1535

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JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 7