The reaction of Co4(CO)12 with Ph2PCH2CH2PPh2. Spectroscopic identification of polymeric products

Silvio Aime; Roberto Gobetto; Giorgio Jannon; Domenico Osella

doi:10.1016/S0022-328X(00)99643-8

The reaction of Co₄(CO)₁₂ with Ph₂PCH₂CH₂PPh₂. Spectroscopic identification of polymeric products

Silvio Aime
, Roberto Gobetto
, Giorgio Jannon
, Domenico Osella

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

Co₄(CO)₁₂ readily undergoes replacement of CO by 1,1-bis(diphenylphosphino)ethane (DPPE) and several derivatives have been characterized. In addition to {[Co₄(CO)₁₁]₂(μ-DPPE)} (I) and [Co₄(CO)₁₀(DPPE)] (II), two polymeric products have been identified by IR and ³¹P NMR spectroscopy. The ¹³C and ³¹P variable temperature NMR spectra of I and II are reported.

Lingua originale	Inglese
pagine (da-a)	C51-C55
Rivista	Journal of Organometallic Chemistry
Volume	309
Numero di pubblicazione	3
DOI	https://doi.org/10.1016/S0022-328X(00)99643-8
Stato di pubblicazione	Pubblicato - 5 ago 1986
Pubblicato esternamente	Sì

Accesso al documento

10.1016/S0022-328X(00)99643-8

Altri file e collegamenti

Link to publication in Scopus

Cita questo

@article{d8f44e2bfc734860bb1af00d3d9a392a,

title = "The reaction of Co4(CO)12 with Ph2PCH2CH2PPh2. Spectroscopic identification of polymeric products",

abstract = "Co4(CO)12 readily undergoes replacement of CO by 1,1-bis(diphenylphosphino)ethane (DPPE) and several derivatives have been characterized. In addition to \{[Co4(CO)11]2(μ-DPPE)\} (I) and [Co4(CO)10(DPPE)] (II), two polymeric products have been identified by IR and 31P NMR spectroscopy. The 13C and 31P variable temperature NMR spectra of I and II are reported.",

author = "Silvio Aime and Roberto Gobetto and Giorgio Jannon and Domenico Osella",

year = "1986",

month = aug,

day = "5",

doi = "10.1016/S0022-328X(00)99643-8",

language = "English",

volume = "309",

pages = "C51--C55",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "3",

}

TY - JOUR

T1 - The reaction of Co4(CO)12 with Ph2PCH2CH2PPh2. Spectroscopic identification of polymeric products

AU - Aime, Silvio

AU - Gobetto, Roberto

AU - Jannon, Giorgio

AU - Osella, Domenico

PY - 1986/8/5

Y1 - 1986/8/5

N2 - Co4(CO)12 readily undergoes replacement of CO by 1,1-bis(diphenylphosphino)ethane (DPPE) and several derivatives have been characterized. In addition to {[Co4(CO)11]2(μ-DPPE)} (I) and [Co4(CO)10(DPPE)] (II), two polymeric products have been identified by IR and 31P NMR spectroscopy. The 13C and 31P variable temperature NMR spectra of I and II are reported.

AB - Co4(CO)12 readily undergoes replacement of CO by 1,1-bis(diphenylphosphino)ethane (DPPE) and several derivatives have been characterized. In addition to {[Co4(CO)11]2(μ-DPPE)} (I) and [Co4(CO)10(DPPE)] (II), two polymeric products have been identified by IR and 31P NMR spectroscopy. The 13C and 31P variable temperature NMR spectra of I and II are reported.

UR - https://www.scopus.com/pages/publications/4243583962

U2 - 10.1016/S0022-328X(00)99643-8

DO - 10.1016/S0022-328X(00)99643-8

M3 - Article

SN - 0022-328X

VL - 309

SP - C51-C55

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3