The reaction of Co4(CO)12 with Ph2PCH2CH2PPh2. Spectroscopic identification of polymeric products

Silvio Aime; Roberto Gobetto; Giorgio Jannon; Domenico Osella

doi:10.1016/S0022-328X(00)99643-8

The reaction of Co₄(CO)₁₂ with Ph₂PCH₂CH₂PPh₂. Spectroscopic identification of polymeric products

Silvio Aime, Roberto Gobetto, Giorgio Jannon, Domenico Osella

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

Co₄(CO)₁₂ readily undergoes replacement of CO by 1,1-bis(diphenylphosphino)ethane (DPPE) and several derivatives have been characterized. In addition to {[Co₄(CO)₁₁]₂(μ-DPPE)} (I) and [Co₄(CO)₁₀(DPPE)] (II), two polymeric products have been identified by IR and ³¹P NMR spectroscopy. The ¹³C and ³¹P variable temperature NMR spectra of I and II are reported.

Lingua originale	Inglese
pagine (da-a)	C51-C55
Rivista	Journal of Organometallic Chemistry
Volume	309
Numero di pubblicazione	3
DOI	https://doi.org/10.1016/S0022-328X(00)99643-8
Stato di pubblicazione	Pubblicato - 5 ago 1986
Pubblicato esternamente	Sì

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10.1016/S0022-328X(00)99643-8

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abstract = "Co4(CO)12 readily undergoes replacement of CO by 1,1-bis(diphenylphosphino)ethane (DPPE) and several derivatives have been characterized. In addition to {[Co4(CO)11]2(μ-DPPE)} (I) and [Co4(CO)10(DPPE)] (II), two polymeric products have been identified by IR and 31P NMR spectroscopy. The 13C and 31P variable temperature NMR spectra of I and II are reported.",

author = "Silvio Aime and Roberto Gobetto and Giorgio Jannon and Domenico Osella",

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AU - Jannon, Giorgio

AU - Osella, Domenico

PY - 1986/8/5

Y1 - 1986/8/5

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AB - Co4(CO)12 readily undergoes replacement of CO by 1,1-bis(diphenylphosphino)ethane (DPPE) and several derivatives have been characterized. In addition to {[Co4(CO)11]2(μ-DPPE)} (I) and [Co4(CO)10(DPPE)] (II), two polymeric products have been identified by IR and 31P NMR spectroscopy. The 13C and 31P variable temperature NMR spectra of I and II are reported.

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