The interpretation of the terminal v(CO) spectra of some tetranuclear carbonyl clusters

Sidney F.A. Kettle, Eliano Diana, Enrico Boccaleri, Pier Luigi Stanghellini

Risultato della ricerca: Contributo su rivistaArticolo in rivistapeer review

Abstract

The recently suggested spherical (SHM) and tensor (THM) harmonic models are applied to the interpretation of the terminal v(CO) spectra of twenty six tetrahedral transition metal clusters containing between four and twelve terminal carbonyl groups. Although the SHM is perhaps the more generally relevant, there are species for which the THM is appropriate as a first approximation. The distinction between the two appears to be associated with a disruption of the band structure of the cluster either by the introduction of heterometal atoms or by the presence of a group - acetate ester, halide or hydride - presumably acting as an electronegative substituent.

Lingua originaleInglese
pagine (da-a)1957-1963
Numero di pagine7
RivistaEuropean Journal of Inorganic Chemistry
Numero di pubblicazione11
Stato di pubblicazionePubblicato - 1999
Pubblicato esternamente

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