The crystal and molecular structure of the [Os(bpy)2 (CO)Cl]+Otf- complex

Gianluca Croce; Marco Milanesio; Davide Viterbo; Claudio Garino; Roberto Gobetto; Carlo Nervi; Luca Salassa

doi:10.1016/j.crci.2005.05.008

The crystal and molecular structure of the [Os(bpy)₂ (CO)Cl]⁺Otf^- complex

Gianluca Croce, Marco Milanesio, Davide Viterbo, Claudio Garino, Roberto Gobetto, Carlo Nervi, Luca Salassa

Dipartimento di Scienze e Innovazione Tecnologica

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

The structure of the [Os(bpy)₂(CO)Cl]⁺ Otf^- complex (where bpy = 2,2′-bipyridine and Otf^- = triflate, CF₃SO₃^-) has been solved by single crystal X-ray diffraction analysis and the NMR technique has been employed for the characterization of the complex in solution. Theoretical calculations have been performed to unravel the structural disorder found in the solid state and for the characterization of the geometric and energetic features of the complex in apolar solution. This study is part of our investigation of Os(bpy)₂(CO) complexes and in this paper we also intend to investigate the effect of different anions on the solid and solution properties of the [Os(bpy)₂(CO)Cl]⁺ cation.

Lingua originale	Inglese
pagine (da-a)	1676-1683
Numero di pagine	8
Rivista	Comptes Rendus Chimie
Volume	8
Numero di pubblicazione	9-10 SPEC. ISS.
DOI	https://doi.org/10.1016/j.crci.2005.05.008
Stato di pubblicazione	Pubblicato - set 2005

Accesso al documento

10.1016/j.crci.2005.05.008

Altri file e collegamenti

Link to publication in Scopus

Cita questo

@article{1930bf6fe6364049928fbf6e54c546c6,

title = "The crystal and molecular structure of the [Os(bpy)2 (CO)Cl]+Otf- complex",

abstract = "The structure of the [Os(bpy)2(CO)Cl]+ Otf- complex (where bpy = 2,2′-bipyridine and Otf- = triflate, CF3SO3-) has been solved by single crystal X-ray diffraction analysis and the NMR technique has been employed for the characterization of the complex in solution. Theoretical calculations have been performed to unravel the structural disorder found in the solid state and for the characterization of the geometric and energetic features of the complex in apolar solution. This study is part of our investigation of Os(bpy)2(CO) complexes and in this paper we also intend to investigate the effect of different anions on the solid and solution properties of the [Os(bpy)2(CO)Cl]+ cation.",

keywords = "Bipyridil ligands, Crystal structure, NMR, Osmium complexes",

author = "Gianluca Croce and Marco Milanesio and Davide Viterbo and Claudio Garino and Roberto Gobetto and Carlo Nervi and Luca Salassa",

year = "2005",

month = sep,

doi = "10.1016/j.crci.2005.05.008",

language = "English",

volume = "8",

pages = "1676--1683",

journal = "Comptes Rendus Chimie",

issn = "1631-0748",

publisher = "Elsevier B.V.",

number = "9-10 SPEC. ISS.",

}

TY - JOUR

T1 - The crystal and molecular structure of the [Os(bpy)2 (CO)Cl]+Otf- complex

AU - Croce, Gianluca

AU - Milanesio, Marco

AU - Viterbo, Davide

AU - Garino, Claudio

AU - Gobetto, Roberto

AU - Nervi, Carlo

AU - Salassa, Luca

PY - 2005/9

Y1 - 2005/9

N2 - The structure of the [Os(bpy)2(CO)Cl]+ Otf- complex (where bpy = 2,2′-bipyridine and Otf- = triflate, CF3SO3-) has been solved by single crystal X-ray diffraction analysis and the NMR technique has been employed for the characterization of the complex in solution. Theoretical calculations have been performed to unravel the structural disorder found in the solid state and for the characterization of the geometric and energetic features of the complex in apolar solution. This study is part of our investigation of Os(bpy)2(CO) complexes and in this paper we also intend to investigate the effect of different anions on the solid and solution properties of the [Os(bpy)2(CO)Cl]+ cation.

AB - The structure of the [Os(bpy)2(CO)Cl]+ Otf- complex (where bpy = 2,2′-bipyridine and Otf- = triflate, CF3SO3-) has been solved by single crystal X-ray diffraction analysis and the NMR technique has been employed for the characterization of the complex in solution. Theoretical calculations have been performed to unravel the structural disorder found in the solid state and for the characterization of the geometric and energetic features of the complex in apolar solution. This study is part of our investigation of Os(bpy)2(CO) complexes and in this paper we also intend to investigate the effect of different anions on the solid and solution properties of the [Os(bpy)2(CO)Cl]+ cation.

KW - Bipyridil ligands

KW - Crystal structure

KW - NMR

KW - Osmium complexes

UR - http://www.scopus.com/inward/record.url?scp=26944446559&partnerID=8YFLogxK

U2 - 10.1016/j.crci.2005.05.008

DO - 10.1016/j.crci.2005.05.008

M3 - Article

SN - 1631-0748

VL - 8

SP - 1676

EP - 1683

JO - Comptes Rendus Chimie

JF - Comptes Rendus Chimie

IS - 9-10 SPEC. ISS.