The Coordination and Transformation of Arene Rings by Transition Metal Carbonyl Cluster Complexes

Sabrina Brait; Stefano Deabate; Selby A.R. Knox; Enrico Sappa

doi:10.1023/A:1016627113620

The Coordination and Transformation of Arene Rings by Transition Metal Carbonyl Cluster Complexes

Sabrina Brait, Stefano Deabate, Selby A.R. Knox, Enrico Sappa

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

A survey of the synthetic pathways and of the reactivity and catalytic activity of transition metal carbonyl clusters substituted with benzyne (and, for comparison, benzene and diene) ligands is given. Cluster-surface analogies are helpful in gaining an understanding of the homogeneous and heterogeneous catalytic behaviour of the clusters.

Lingua originale	Inglese
pagine (da-a)	139-173
Numero di pagine	35
Rivista	Journal of Cluster Science
Volume	12
Numero di pubblicazione	1
DOI	https://doi.org/10.1023/A:1016627113620
Stato di pubblicazione	Pubblicato - 2001
Pubblicato esternamente	Sì

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10.1023/A:1016627113620

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title = "The Coordination and Transformation of Arene Rings by Transition Metal Carbonyl Cluster Complexes",

abstract = "A survey of the synthetic pathways and of the reactivity and catalytic activity of transition metal carbonyl clusters substituted with benzyne (and, for comparison, benzene and diene) ligands is given. Cluster-surface analogies are helpful in gaining an understanding of the homogeneous and heterogeneous catalytic behaviour of the clusters.",

keywords = "Benzyne ligands, Hydrogenation catalysis (homogeneous, solid-gas, heterogeneous), Reactivity; cluster-surface analogy, Transition metal clusters",

author = "Sabrina Brait and Stefano Deabate and Knox, \{Selby A.R.\} and Enrico Sappa",

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AU - Sappa, Enrico

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AB - A survey of the synthetic pathways and of the reactivity and catalytic activity of transition metal carbonyl clusters substituted with benzyne (and, for comparison, benzene and diene) ligands is given. Cluster-surface analogies are helpful in gaining an understanding of the homogeneous and heterogeneous catalytic behaviour of the clusters.

KW - Benzyne ligands

KW - Hydrogenation catalysis (homogeneous, solid-gas, heterogeneous)

KW - Reactivity; cluster-surface analogy

KW - Transition metal clusters

UR - https://www.scopus.com/pages/publications/0035593988

U2 - 10.1023/A:1016627113620

DO - 10.1023/A:1016627113620

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The Coordination and Transformation of Arene Rings by Transition Metal Carbonyl Cluster Complexes

Abstract

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