The bond analysis techniques (ELF and maximum probability domains) application to a family of models relevant to bio-inorganic chemistry

  • Mauro Causà
  • , Maddalena D'Amore
  • , Carmine Garzillo
  • , Francesco Gentile
  • , Andreas Savin

Risultato della ricerca: Capitolo in libro/report/atti di convegnoContributo in volume (Capitolo o Saggio)peer review

Abstract

Electron Localization Function (ELF) and Maximum Probability Domain (MPD) analyses have been applied to model metal - porphyrins and show compatible and complementary results. ELF basins are quite different from MPDs, but are a necessary starting point for optimizing them. The analyses of the bond between the metal and porphyrin do not show significant differences between nontransition and transition metals. In all the cases considered, we find signatures characteristic of essentially ionic bonds.

Lingua originaleInglese
Titolo della pubblicazione ospiteApplications of Density Functional Theory to Biological and Bioinorganic Chemistry
EditoreSpringer Verlag
Pagine119-142
Numero di pagine24
ISBN (stampa)9783642327490
DOI
Stato di pubblicazionePubblicato - 2013
Pubblicato esternamente

Serie di pubblicazioni

NomeStructure and Bonding
Volume150
ISSN (stampa)0081-5993
ISSN (elettronico)1616-8550

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