TY - JOUR
T1 - Synthesis of the alkoxo(hydrido)-clusters [Ru3(µ-H)(CO)10(µ-OR)][R = Me, Et, Prn, or Bun] catalysed by dinuclear carbonyl iron complexes
AU - AIME, S
AU - BOTTA, Mauro
AU - GOBETTO, R
AU - OSELLA, Domenico
AU - PADOVAN, F.
PY - 1987
Y1 - 1987
N2 - The use of dinuclear carbonyl iron complexes, namely [Fe2(η5-C5H5) 2(CO)4] and [Fe2(CO)4(PPh3)2(SMe)2], as catalysts in reactions of CO replacement by the weak nucleophilic molecules ROH (R = Me, Et, Prn, or Bun) allows the isolation of the novel series of derivatives [Ru3(μ-H)(CO)10(μ-OR)], previously inaccessible by thermal routes.
AB - The use of dinuclear carbonyl iron complexes, namely [Fe2(η5-C5H5) 2(CO)4] and [Fe2(CO)4(PPh3)2(SMe)2], as catalysts in reactions of CO replacement by the weak nucleophilic molecules ROH (R = Me, Et, Prn, or Bun) allows the isolation of the novel series of derivatives [Ru3(μ-H)(CO)10(μ-OR)], previously inaccessible by thermal routes.
UR - https://iris.uniupo.it/handle/11579/31233
U2 - 10.1039/dt9870000253
DO - 10.1039/dt9870000253
M3 - Article
SN - 0300-9246
SP - 253
EP - 254
JO - Journal of the Chemical Society. Dalton Transactions
JF - Journal of the Chemical Society. Dalton Transactions
IS - 1
ER -