Synthesis of Enantiomerically Pure 24-Alkylsterol Side Chains, in Both Enantiomeric Forms, Starting from (R)-( + )-Limonene

Francesco Nicotra, Luigi Panza, Fiamma Ronchetti, Giovanni Russo, Lucio Toma

Risultato della ricerca: Contributo su rivistaArticolo in rivistapeer review

Abstract

Three couples of enantiomeric synthons corresponding to six 24-alkylsterol side chains, (R)- and (S)-1-bromo-3,4-dimethylpentane, (R)- and (S)-1-bromo-3-ethyl-4-methylpentane, and (R)- and (S)-5-(acetyloxy)-1-bromo-3-(1-methylethyl)pentane, were synthesized from the same chiral intermediate, (R)-5-(acyloxy)-3-(1-methylethyl)pentan-1-ol, readily obtainable from (R)-(+)-limonene.

Lingua originaleInglese
pagine (da-a)1272-1276
Numero di pagine5
RivistaJournal of Organic Chemistry
Volume51
Numero di pubblicazione8
DOI
Stato di pubblicazionePubblicato - 1986
Pubblicato esternamente

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