Synthesis of 1-(α-D-glucopyranosyl)-1-deoxy-D-fructose a non-metabolisable analogue of sucrose

Marta Carcano; Francesco Nicotra; Luigi Panza; Giovanni Russo

doi:10.1039/C39890000642

Synthesis of 1-(α-D-glucopyranosyl)-1-deoxy-D-fructose a non-metabolisable analogue of sucrose

Marta Carcano
, Francesco Nicotra
, Luigi Panza
, Giovanni Russo

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

Reaction of the ylide (6), obtained from the known 1′-(2,3,4,6-tetra- O-benzyl-α-D-glucopyranosyl)prop-2-ene (2), with 2,3-O-isopropylidene-D- glyceraldehyde, osmylation of the product (7), and deprotection, affords 1-(α-D-glucopyranosyl)-1-deoxy-D-fructose (1), a C-disaccharide structurally related to sucrose.

Lingua originale	Inglese
pagine (da-a)	642-643
Numero di pagine	2
Rivista	Chemical Communications
Numero di pubblicazione	10
DOI	https://doi.org/10.1039/C39890000642
Stato di pubblicazione	Pubblicato - 1989
Pubblicato esternamente	Sì

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title = "Synthesis of 1-(α-D-glucopyranosyl)-1-deoxy-D-fructose a non-metabolisable analogue of sucrose",

abstract = "Reaction of the ylide (6), obtained from the known 1′-(2,3,4,6-tetra- O-benzyl-α-D-glucopyranosyl)prop-2-ene (2), with 2,3-O-isopropylidene-D- glyceraldehyde, osmylation of the product (7), and deprotection, affords 1-(α-D-glucopyranosyl)-1-deoxy-D-fructose (1), a C-disaccharide structurally related to sucrose.",

author = "Marta Carcano and Francesco Nicotra and Luigi Panza and Giovanni Russo",

year = "1989",

doi = "10.1039/C39890000642",

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journal = "Chemical Communications",

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AU - Panza, Luigi

AU - Russo, Giovanni

PY - 1989

Y1 - 1989

N2 - Reaction of the ylide (6), obtained from the known 1′-(2,3,4,6-tetra- O-benzyl-α-D-glucopyranosyl)prop-2-ene (2), with 2,3-O-isopropylidene-D- glyceraldehyde, osmylation of the product (7), and deprotection, affords 1-(α-D-glucopyranosyl)-1-deoxy-D-fructose (1), a C-disaccharide structurally related to sucrose.

AB - Reaction of the ylide (6), obtained from the known 1′-(2,3,4,6-tetra- O-benzyl-α-D-glucopyranosyl)prop-2-ene (2), with 2,3-O-isopropylidene-D- glyceraldehyde, osmylation of the product (7), and deprotection, affords 1-(α-D-glucopyranosyl)-1-deoxy-D-fructose (1), a C-disaccharide structurally related to sucrose.

UR - https://www.scopus.com/pages/publications/37049078759

U2 - 10.1039/C39890000642

DO - 10.1039/C39890000642

M3 - Article

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Synthesis of 1-(α-D-glucopyranosyl)-1-deoxy-D-fructose a non-metabolisable analogue of sucrose

Abstract

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