TY - JOUR
T1 - Synthesis of 1-(α-D-glucopyranosyl)-1-deoxy-D-fructose a non-metabolisable analogue of sucrose
AU - Carcano, Marta
AU - Nicotra, Francesco
AU - Panza, Luigi
AU - Russo, Giovanni
PY - 1989
Y1 - 1989
N2 - Reaction of the ylide (6), obtained from the known 1′-(2,3,4,6-tetra- O-benzyl-α-D-glucopyranosyl)prop-2-ene (2), with 2,3-O-isopropylidene-D- glyceraldehyde, osmylation of the product (7), and deprotection, affords 1-(α-D-glucopyranosyl)-1-deoxy-D-fructose (1), a C-disaccharide structurally related to sucrose.
AB - Reaction of the ylide (6), obtained from the known 1′-(2,3,4,6-tetra- O-benzyl-α-D-glucopyranosyl)prop-2-ene (2), with 2,3-O-isopropylidene-D- glyceraldehyde, osmylation of the product (7), and deprotection, affords 1-(α-D-glucopyranosyl)-1-deoxy-D-fructose (1), a C-disaccharide structurally related to sucrose.
UR - http://www.scopus.com/inward/record.url?scp=37049078759&partnerID=8YFLogxK
U2 - 10.1039/C39890000642
DO - 10.1039/C39890000642
M3 - Article
SN - 0022-4936
SP - 642
EP - 643
JO - Chemical Communications
JF - Chemical Communications
IS - 10
ER -