Abstract
The synthesis of a novel macrocyclic ligand containing nine potential coordination sites (six nitrogens and three oxygens) formed by a triazacyclododecane ring trisubstituted with -CH2-CH2-N(CH2Ph)-CH2COOH groups is reported. The protonation scheme of this ligand has been elucidated by measuring the proton NMR shifts of the various methylenic resonances upon changing the pH of the solution. This ligand affords stable metal complexes with Cd2+ ion, whose 1H- and 13C-NMR spectra suggest a remarkable kinetic inertia and stereochemical rigidity.
Lingua originale | Inglese |
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pagine (da-a) | 94-98 |
Numero di pagine | 5 |
Rivista | Recueil des Travaux Chimiques des Pays-Bas-Journal of the Royal Netherlands |
Volume | 115 |
Numero di pubblicazione | 1 |
DOI | |
Stato di pubblicazione | Pubblicato - gen 1996 |
Pubblicato esternamente | Sì |