Surface Structure of Ni/MgO Catalysts: Effects of Carbon and Hydrogen on the Reactivity Towards CO. HRTEM and FTIR Studies

G. MARTRA; Leonardo MARCHESE; F. ARENA; A. PARMALIANA; S. COLUCCIA

Surface Structure of Ni/MgO Catalysts: Effects of Carbon and Hydrogen on the Reactivity Towards CO. HRTEM and FTIR Studies

G. MARTRA, Leonardo MARCHESE, F. ARENA, A. PARMALIANA, S. COLUCCIA

Dipartimento di Scienze e Innovazione Tecnologica

Risultato della ricerca: Contributo su rivista › Articolo in rivista

Abstract

CO adsorption on high loading Ni/MgO samples treated at 800 and 900°C has been studied by using IR spectroscopy. Linear and bridged monocarbonyls are produced under low CO pressure and the Boudouard reaction occurs producing C, adsorbed on the metal particles, and CO₂, stabilized on the MgO matrix. Effects of hydrogen and carbon on surface reactivity have been studied. The morphology of the catalysts and of carbonaceous deposits produced by heating in CO at high temperature are examined by HRTEM.

Lingua originale	Inglese
pagine (da-a)	63
Numero di pagine	63
Rivista	Topics in Catalysis
Volume	1
Stato di pubblicazione	Pubblicato - 1994

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title = "Surface Structure of Ni/MgO Catalysts: Effects of Carbon and Hydrogen on the Reactivity Towards CO. HRTEM and FTIR Studies",

abstract = "CO adsorption on high loading Ni/MgO samples treated at 800 and 900°C has been studied by using IR spectroscopy. Linear and bridged monocarbonyls are produced under low CO pressure and the Boudouard reaction occurs producing C, adsorbed on the metal particles, and CO2, stabilized on the MgO matrix. Effects of hydrogen and carbon on surface reactivity have been studied. The morphology of the catalysts and of carbonaceous deposits produced by heating in CO at high temperature are examined by HRTEM.",

author = "G. MARTRA and Leonardo MARCHESE and F. ARENA and A. PARMALIANA and S. COLUCCIA",

year = "1994",

language = "English",

volume = "1",

pages = "63",

journal = "Topics in Catalysis",

issn = "1022-5528",

publisher = "Springer",

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TY - JOUR

T1 - Surface Structure of Ni/MgO Catalysts: Effects of Carbon and Hydrogen on the Reactivity Towards CO. HRTEM and FTIR Studies

AU - MARTRA, G.

AU - MARCHESE, Leonardo

AU - ARENA, F.

AU - PARMALIANA, A.

AU - COLUCCIA, S.

PY - 1994

Y1 - 1994

N2 - CO adsorption on high loading Ni/MgO samples treated at 800 and 900°C has been studied by using IR spectroscopy. Linear and bridged monocarbonyls are produced under low CO pressure and the Boudouard reaction occurs producing C, adsorbed on the metal particles, and CO2, stabilized on the MgO matrix. Effects of hydrogen and carbon on surface reactivity have been studied. The morphology of the catalysts and of carbonaceous deposits produced by heating in CO at high temperature are examined by HRTEM.

AB - CO adsorption on high loading Ni/MgO samples treated at 800 and 900°C has been studied by using IR spectroscopy. Linear and bridged monocarbonyls are produced under low CO pressure and the Boudouard reaction occurs producing C, adsorbed on the metal particles, and CO2, stabilized on the MgO matrix. Effects of hydrogen and carbon on surface reactivity have been studied. The morphology of the catalysts and of carbonaceous deposits produced by heating in CO at high temperature are examined by HRTEM.

UR - https://iris.uniupo.it/handle/11579/4046

M3 - Article

SN - 1022-5528

VL - 1

SP - 63

JO - Topics in Catalysis

JF - Topics in Catalysis

ER -

Surface Structure of Ni/MgO Catalysts: Effects of Carbon and Hydrogen on the Reactivity Towards CO. HRTEM and FTIR Studies

Abstract

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