13C N.M.R. spectra of highly 13CO-enriched metal carbonyls: Observation of 2JCC cis coupling constants

Silvio Aime; Domenico Osella

doi:10.1039/c39810000300

¹³C N.M.R. spectra of highly ¹³CO-enriched metal carbonyls: Observation of ²J_CC cis coupling constants

Silvio Aime
, Domenico Osella

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

¹³C N.m.r. spectra of metal carbonyls (>60% ¹³CO-enriched) allow the first observation of ²J _CC cis values which are an order of magnitude smaller than ²J_CC trans; this technique is also useful in the assignment of CO resonances as is shown in the case of H₂Os ₃(CO)₁₀.

Lingua originale	Inglese
pagine (da-a)	300-302
Numero di pagine	3
Rivista	Journal of the Chemical Society D: Chemical Communications
Numero di pubblicazione	6
DOI	https://doi.org/10.1039/c39810000300
Stato di pubblicazione	Pubblicato - 1981
Pubblicato esternamente	Sì

Accesso al documento

10.1039/c39810000300

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title = "13C N.M.R. spectra of highly 13CO-enriched metal carbonyls: Observation of 2JCC cis coupling constants",

abstract = "13C N.m.r. spectra of metal carbonyls (>60\% 13CO-enriched) allow the first observation of 2J CC cis values which are an order of magnitude smaller than 2JCC trans; this technique is also useful in the assignment of CO resonances as is shown in the case of H2Os 3(CO)10.",

author = "Silvio Aime and Domenico Osella",

year = "1981",

doi = "10.1039/c39810000300",

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T1 - 13C N.M.R. spectra of highly 13CO-enriched metal carbonyls

T2 - Observation of 2JCC cis coupling constants

AU - Aime, Silvio

AU - Osella, Domenico

PY - 1981

Y1 - 1981

N2 - 13C N.m.r. spectra of metal carbonyls (>60% 13CO-enriched) allow the first observation of 2J CC cis values which are an order of magnitude smaller than 2JCC trans; this technique is also useful in the assignment of CO resonances as is shown in the case of H2Os 3(CO)10.

AB - 13C N.m.r. spectra of metal carbonyls (>60% 13CO-enriched) allow the first observation of 2J CC cis values which are an order of magnitude smaller than 2JCC trans; this technique is also useful in the assignment of CO resonances as is shown in the case of H2Os 3(CO)10.

UR - https://www.scopus.com/pages/publications/37049096673

U2 - 10.1039/c39810000300

DO - 10.1039/c39810000300

M3 - Article

SN - 0022-4936

SP - 300

EP - 302

JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 6