TY - JOUR
T1 - Sulfur‐Centered Radicals in Visible Light Isocyanide Photochemistry
AU - Russo, Camilla
AU - Brunelli, Francesca
AU - TRON, Gian Cesare
AU - Giustiniano, Mariateresa
PY - 2023
Y1 - 2023
N2 - Sulfur-centered radicals have a key role in a plethora of synthetic organic transformations, whose scope has been further expanded thanks to the possibility to generate such species under visible light photocatalytic conditions. This review focuses on those transformations involving isocyanides and sulfur-centered radicals with the aim to highlight the chemical space accessible, both in terms of complexity and diversity, and the mechanistic rational underpinning the current and future development of such chemical methodologies.Sulfur-centered radicals have a key role in a plethora of synthetic transformations, whose scope is ever-expanding thanks to visible light photocatalysis. The current review focuses on those transformations involving isocyanides and S-centered radicals and aims to highlight the chemical space accessible and the mechanistic rational underpinning current and future developments.image
AB - Sulfur-centered radicals have a key role in a plethora of synthetic organic transformations, whose scope has been further expanded thanks to the possibility to generate such species under visible light photocatalytic conditions. This review focuses on those transformations involving isocyanides and sulfur-centered radicals with the aim to highlight the chemical space accessible, both in terms of complexity and diversity, and the mechanistic rational underpinning the current and future development of such chemical methodologies.Sulfur-centered radicals have a key role in a plethora of synthetic transformations, whose scope is ever-expanding thanks to visible light photocatalysis. The current review focuses on those transformations involving isocyanides and S-centered radicals and aims to highlight the chemical space accessible and the mechanistic rational underpinning current and future developments.image
KW - sulfur-centered radicals
KW - isocyanides
KW - visible light photocatalysis
KW - organosulfur compounds
KW - isocyanobiaryls
KW - sulfur-centered radicals
KW - isocyanides
KW - visible light photocatalysis
KW - organosulfur compounds
KW - isocyanobiaryls
UR - https://iris.uniupo.it/handle/11579/178868
U2 - 10.1002/ejoc.202300743
DO - 10.1002/ejoc.202300743
M3 - Article
SN - 1434-193X
VL - 26
JO - European Journal of Organic Chemistry
JF - European Journal of Organic Chemistry
IS - 45
ER -