Stereoselective Shi-type epoxidation with 3-oxo-4,6-O-benzylidene pyranoside catalysts: unveiling the role of carbohydrate skeletons

Keyphrases

• Epoxidation 100%
• Benzylidene 100%
• Epoxides 100%
• Stereoselectivity 100%
• Carbohydrates 100%
• Unveiling 100%
• Pyranosides 100%
• Asymmetric Epoxidation 100%
• DFT Calculations 50%
• Organic Synthesis 50%
• Protecting Groups 50%
• Enantiomeric 50%
• Galactose 50%
• High Conversion 50%
• Ketones 50%
• Organocatalyst 50%
• Enantioselectivity 50%
• Olefins 50%
• Secondary Interactions 50%
• Delicate Balance 50%
• Stereoselective Epoxidation 50%

Chemistry

• epoxidation 100%
• Pyranoside 100%
• Epoxide 40%
• Alkene 20%
• Protecting Groups 20%
• Organocatalyst 20%
• Enantioselectivity 20%
• Ketones 20%
• Enantiomer 20%
• Density Functional Theory 20%
• Galactose 20%
• Benzylidene Group 20%

Chemical Engineering

• Olefin 100%