TY - JOUR
T1 - Sonochemical Synthesis and Characterization of the New Plate-Shaped Lead(II)-Iodo Coordination Polymer
T2 - A Precursor to Produce a Pure Phase Nano-Sized Lead(II) Oxide
AU - Mirtamizdoust, Babak
AU - Shaabani, Behrouz
AU - Khandar, Aliakbar
AU - Pourradi, Hadi
AU - Abbasityula, Yunes
AU - Goudarziafshar, Hamid
AU - Viterbo, Davide
AU - Croce, Gianluca
AU - Hojati-Talemi, Pejman
N1 - Funding Information:
Acknowledgments The authors acknowledge financial support by University of Tabriz Research Council (Project number sad/27/1391-3) and Università del Piemonte Orientale is gratefully acknowledged.
PY - 2012/11
Y1 - 2012/11
N2 - Preparation of plate-shaped nanostructures of a new 1D polymeric lead(II) complex containing the Pb 2-(μ-I) 2 motif, [Pb(neo)I 2] n,(1) where neo is the abbreviation of neocuproine, using a sonochemical method is described. The new coordination polymer is characterized by scanning electron microscopy, X-ray diffraction (XRD), elemental analysis and infrared spectroscopy. The single crystalline material is obtained using a heat gradient applied to a solution of the reagents. Single-crystal XRD analysis indicates that a coordination number of six for Pb II ions, (i. e., PbN 2I 4) with an asymmetrical coordination sphere and "stereo-chemically active" electron lone pairs. They also show that the chains interact with each other through π-π stacking interactions creating a 3D framework. PbO nanoparticles are obtained by thermolysis of 1 at 180 °C with oleic acid as a surfactant. Scanning electron microscopy confirms formation of PbO particles with a size of ~25 nm.
AB - Preparation of plate-shaped nanostructures of a new 1D polymeric lead(II) complex containing the Pb 2-(μ-I) 2 motif, [Pb(neo)I 2] n,(1) where neo is the abbreviation of neocuproine, using a sonochemical method is described. The new coordination polymer is characterized by scanning electron microscopy, X-ray diffraction (XRD), elemental analysis and infrared spectroscopy. The single crystalline material is obtained using a heat gradient applied to a solution of the reagents. Single-crystal XRD analysis indicates that a coordination number of six for Pb II ions, (i. e., PbN 2I 4) with an asymmetrical coordination sphere and "stereo-chemically active" electron lone pairs. They also show that the chains interact with each other through π-π stacking interactions creating a 3D framework. PbO nanoparticles are obtained by thermolysis of 1 at 180 °C with oleic acid as a surfactant. Scanning electron microscopy confirms formation of PbO particles with a size of ~25 nm.
KW - Lead(II)
KW - Nano coordination polymer
KW - Nano oxide
KW - Plate-shape
UR - http://www.scopus.com/inward/record.url?scp=84867662074&partnerID=8YFLogxK
U2 - 10.1007/s10904-012-9754-0
DO - 10.1007/s10904-012-9754-0
M3 - Article
SN - 1574-1443
VL - 22
SP - 1293
EP - 1299
JO - Journal of Inorganic and Organometallic Polymers and Materials
JF - Journal of Inorganic and Organometallic Polymers and Materials
IS - 6
ER -