Solid state adducts between C60 and decamethylferrocene

ALDO ARRAIS; E. DIANA; R. GOBETTO; Marco MILANESIO; Davide VITERBO; Pier Luigi STANGHELLINI

Solid state adducts between C60 and decamethylferrocene

ALDO ARRAIS, E. DIANA, R. GOBETTO, Marco MILANESIO, Davide VITERBO, Pier Luigi STANGHELLINI

Dipartimento di Scienze e Innovazione Tecnologica

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

Co-deposition from concentrated solutions of C₆₀ and Fe[C₅(CH₃)₅]₂ affords two solid products in different yields. The major product 1, in the form of regular shaped crystals, has been investigated by X-ray diffraction, ¹³C CPMAS NMR and vibrational spectroscopy, which showed it to be a cocrystalline adduct of C₆₀ and Fe[C₅(CH₃)₅]₂ with no significant electron charge transfer between the two building blocks. The minor product 2, in the form of an amorphous powder, has been investigated by vibrational techniques. Both IR and Raman spectra are consistent with a solid structure in which electron transfer between the two units appears to be possible.

Lingua originale	Inglese
pagine (da-a)	1186-1192
Numero di pagine	7
Rivista	European Journal of Inorganic Chemistry
Volume	6
Stato di pubblicazione	Pubblicato - 2003

Accesso al documento

http://hdl.handle.net/11579/30426

Altri file e collegamenti

handle

Cita questo

@article{b689ea341bc24117a441ab6acddbddfb,

title = "Solid state adducts between C60 and decamethylferrocene",

abstract = "Co-deposition from concentrated solutions of C60 and Fe[C5(CH3)5]2 affords two solid products in different yields. The major product 1, in the form of regular shaped crystals, has been investigated by X-ray diffraction, 13C CPMAS NMR and vibrational spectroscopy, which showed it to be a cocrystalline adduct of C60 and Fe[C5(CH3)5]2 with no significant electron charge transfer between the two building blocks. The minor product 2, in the form of an amorphous powder, has been investigated by vibrational techniques. Both IR and Raman spectra are consistent with a solid structure in which electron transfer between the two units appears to be possible.",

author = "ALDO ARRAIS and E. DIANA and R. GOBETTO and Marco MILANESIO and Davide VITERBO and STANGHELLINI, \{Pier Luigi\}",

year = "2003",

language = "English",

volume = "6",

pages = "1186--1192",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

}

TY - JOUR

T1 - Solid state adducts between C60 and decamethylferrocene

AU - ARRAIS, ALDO

AU - DIANA, E.

AU - GOBETTO, R.

AU - MILANESIO, Marco

AU - VITERBO, Davide

AU - STANGHELLINI, Pier Luigi

PY - 2003

Y1 - 2003

N2 - Co-deposition from concentrated solutions of C60 and Fe[C5(CH3)5]2 affords two solid products in different yields. The major product 1, in the form of regular shaped crystals, has been investigated by X-ray diffraction, 13C CPMAS NMR and vibrational spectroscopy, which showed it to be a cocrystalline adduct of C60 and Fe[C5(CH3)5]2 with no significant electron charge transfer between the two building blocks. The minor product 2, in the form of an amorphous powder, has been investigated by vibrational techniques. Both IR and Raman spectra are consistent with a solid structure in which electron transfer between the two units appears to be possible.

AB - Co-deposition from concentrated solutions of C60 and Fe[C5(CH3)5]2 affords two solid products in different yields. The major product 1, in the form of regular shaped crystals, has been investigated by X-ray diffraction, 13C CPMAS NMR and vibrational spectroscopy, which showed it to be a cocrystalline adduct of C60 and Fe[C5(CH3)5]2 with no significant electron charge transfer between the two building blocks. The minor product 2, in the form of an amorphous powder, has been investigated by vibrational techniques. Both IR and Raman spectra are consistent with a solid structure in which electron transfer between the two units appears to be possible.

UR - https://iris.uniupo.it/handle/11579/30426

M3 - Article

SN - 1434-1948

VL - 6

SP - 1186

EP - 1192

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

ER -

Solid state adducts between C60 and decamethylferrocene

Abstract

Accesso al documento

Altri file e collegamenti

Fingerprint

Cita questo