Solid-state adducts between C60 and decamethylferrocene

Aldo Arrais, Eliano Diana, Roberto Gobetto, Marco Milanesio, Davide Viterbo, Pier Luigi Stanghellini

Risultato della ricerca: Contributo su rivistaArticolo in rivistapeer review

Abstract

Co-deposition from concentrated solutions of C60 and Fe[C5(CH3)5]2 affords two solid products in different yields. The major product 1, in the form of regular shaped crystals, has been investigated by X-ray diffraction, 13C CPMAS NMR and vibrational spectroscopy, which showed it to be a cocrystalline adduct of C60 and Fe[C5(CH3)5]2 with no significant electron charge transfer between the two building blocks. The minor product 2, in the form of an amorphous powder, has been investigated by vibrational techniques. Both IR and Raman spectra are consistent with a solid structure in which electron transfer between the two units appears to be possible.

Lingua originaleInglese
pagine (da-a)1186-1192
Numero di pagine7
RivistaEuropean Journal of Inorganic Chemistry
Numero di pubblicazione6
DOI
Stato di pubblicazionePubblicato - mar 2003

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