Relaxometric and solution NMR structural studies on ditopic lanthanide(iii) complexes of a phosphinate analogue of DOTA with a fast rate of water exchange

Keyphrases

• Relaxivity 100%
• 17O NMR 100%
• Water Exchange 100%
• Lanthanide Complexes 100%
• Ditopic Complex 100%
• Ditopic 100%
• Phosphinate 100%
• Solution NMR 100%
• Fast Rates 100%
• Variable Temperature 50%
• Eu3+ 50%
• 1H NMR Spectra 50%
• Solution Structure 50%
• Isomeric 50%
• Structural Information 50%
• Internal Rotation 50%
• NMR Relaxation 50%
• Gd(III) 50%
• Water Molecule 50%
• NMR Relaxometry 50%
• NMR Spectroscopy 50%
• NMRD Profiles 50%
• Molecular Size 50%
• Inner Sphere 50%
• Dysprosium 50%
• Rotational Correlation Time 50%
• Triacetate 50%
• 2-complex 50%
• NMR Shifts 50%
• 31P NMR Spectra 50%
• Thiourea 50%
• Ln3+ Ions 50%
• Simultaneous Fitting 50%
• Homodinuclear 50%
• Mixed Complexes 50%
• Control Parameters 50%
• High Abundance 50%
• Ditopic Ligand 50%
• Heterodinuclear 50%
• Compact Solutions 50%
• First Coordination Sphere 50%

Chemistry

• 17O NMR Spectroscopy 100%
• Lanthanoid Atom 100%
• DOTA 100%
• Phosphinate 100%
• Solution NMR 100%
• Rare Earth Element 100%
• NMR Spectroscopy 50%
• 1H NMR Spectrum 50%
• Nuclear Magnetic Resonance Relaxation 50%
• Internal Rotation 50%
• Coordination Sphere 50%
• Molecular Size 50%
• Dysprosium 50%
• 31P NMR Spectrum 50%
• Thiourea 50%
• solution structure 50%