Reinvestigation of the Electrochemical Behavior of the Co2(CO)6(ethynylestradiol) Complex. Evidence of Efficient Recombination of the Electrogenerated Fragments

Domenico Osella; Jan Fiedler

doi:10.1021/om00059a061

Reinvestigation of the Electrochemical Behavior of the Co₂(CO)₆(ethynylestradiol) Complex. Evidence of Efficient Recombination of the Electrogenerated Fragments

Domenico Osella, Jan Fiedler

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

The electrochemical behavior of Co₂(CO)₆(ethynylestradiol) complexes has been reinvestigated by means of electrochemical and spectroscopic techniques. The electrogenerated [Co₂(CO)₆(ethynylestradiol)]^- monoanion is very unstable and undergoes fast cleavage of the C–Co bond, producing Co(CO)₄^-. An efficient recombination Co(CO)4^• radical (produced from reoxidation of Co(CO)₄^-) with the [Co(CO)₂(ethynylestradiol)]^• radical, adsorbed on the electrode, regenerates almost qualitatively the parent complex, in the chemical time scale.

Lingua originale	Inglese
pagine (da-a)	3875-3878
Numero di pagine	4
Rivista	Organometallics
Volume	11
Numero di pubblicazione	11
DOI	https://doi.org/10.1021/om00059a061
Stato di pubblicazione	Pubblicato - 1 nov 1992
Pubblicato esternamente	Sì

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10.1021/om00059a061

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title = "Reinvestigation of the Electrochemical Behavior of the Co2(CO)6(ethynylestradiol) Complex. Evidence of Efficient Recombination of the Electrogenerated Fragments",

abstract = "The electrochemical behavior of Co2(CO)6(ethynylestradiol) complexes has been reinvestigated by means of electrochemical and spectroscopic techniques. The electrogenerated [Co2(CO)6(ethynylestradiol)]- monoanion is very unstable and undergoes fast cleavage of the C–Co bond, producing Co(CO)4-. An efficient recombination Co(CO)4• radical (produced from reoxidation of Co(CO)4-) with the [Co(CO)2(ethynylestradiol)]• radical, adsorbed on the electrode, regenerates almost qualitatively the parent complex, in the chemical time scale.",

author = "Domenico Osella and Jan Fiedler",

year = "1992",

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doi = "10.1021/om00059a061",

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AU - Fiedler, Jan

PY - 1992/11/1

Y1 - 1992/11/1

N2 - The electrochemical behavior of Co2(CO)6(ethynylestradiol) complexes has been reinvestigated by means of electrochemical and spectroscopic techniques. The electrogenerated [Co2(CO)6(ethynylestradiol)]- monoanion is very unstable and undergoes fast cleavage of the C–Co bond, producing Co(CO)4-. An efficient recombination Co(CO)4• radical (produced from reoxidation of Co(CO)4-) with the [Co(CO)2(ethynylestradiol)]• radical, adsorbed on the electrode, regenerates almost qualitatively the parent complex, in the chemical time scale.

AB - The electrochemical behavior of Co2(CO)6(ethynylestradiol) complexes has been reinvestigated by means of electrochemical and spectroscopic techniques. The electrogenerated [Co2(CO)6(ethynylestradiol)]- monoanion is very unstable and undergoes fast cleavage of the C–Co bond, producing Co(CO)4-. An efficient recombination Co(CO)4• radical (produced from reoxidation of Co(CO)4-) with the [Co(CO)2(ethynylestradiol)]• radical, adsorbed on the electrode, regenerates almost qualitatively the parent complex, in the chemical time scale.

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U2 - 10.1021/om00059a061

DO - 10.1021/om00059a061

M3 - Article

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JO - Organometallics

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