Rational design of single-site heterogeneous catalysts: Towards high chemo-, regio-and stereoselectivity

Vladimiro Dal Santo, Matteo Guidotti, Rinaldo Psaro, Leonardo Marchese, Fabio Carniato, Chiara Bisio

Risultato della ricerca: Contributo su rivistaArticolo in rivistapeer review

Abstract

The main methods for the design and preparation of single-site heterogeneous catalysts on inorganic oxide supports are described and reviewed. Catalytically active metal sites can be either introduced into the framework of porous materials via direct synthesis or added to a pre-existing support by post-synthesis techniques. Particular attention is paid to selected examples where the geometry, the nature and the chemical surroundings of the active single site is a key factor to obtain catalytic systems with enhanced chemo-, regioand stereoselectivity. The ever-increasing capabilities of 'nanoarchitecture' at molecular level enable chemists to build ideal catalysts for the sustainable transformation of bulky and high added-value molecules.

Lingua originaleInglese
pagine (da-a)1904-1926
Numero di pagine23
RivistaProceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences
Volume468
Numero di pubblicazione2143
DOI
Stato di pubblicazionePubblicato - 8 lug 2012

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