Probing delocalisation across highly ethynylated mono and dinuclear Pt(II) tethers containing nitrogroups and organic models as redox active probes: X-ray crystal structure of trans-[Pt(CC-C6H4NO2) 2(PPh3)2]

Mauro Ravera; Rosaria D'Amato; Annalisa Guerri

doi:10.1016/j.jorganchem.2005.02.014

Probing delocalisation across highly ethynylated mono and dinuclear Pt(II) tethers containing nitrogroups and organic models as redox active probes: X-ray crystal structure of trans-[Pt(CC-C₆H₄NO₂) ₂(PPh₃)₂]

Mauro Ravera
, Rosaria D'Amato
, Annalisa Guerri

Dipartimento di Scienze e Innovazione Tecnologica

Risultato della ricerca: Contributo su rivista › Breve indagine › peer review

Abstract

The electrochemical study on Pt(II) organometallic and organic ethynylated compounds bearing nitro substituents in the phenyl groups has been performed, demonstrating that the presence of severe chemical irreversibility accompanying the electron transfer, preclude an evaluation of the electronic communication between redox active centres. The X-ray structure of the complex trans-[Pt(CC-C₆H₄NO₂)₂(PPh ₃)₂] is showed.

Lingua originale	Inglese
pagine (da-a)	2376-2380
Numero di pagine	5
Rivista	Journal of Organometallic Chemistry
Volume	690
Numero di pubblicazione	9
DOI	https://doi.org/10.1016/j.jorganchem.2005.02.014
Stato di pubblicazione	Pubblicato - 29 apr 2005

Accesso al documento

10.1016/j.jorganchem.2005.02.014

Cita questo

@article{ec7d318b076e4064a950b74d0bfe34fa,

title = "Probing delocalisation across highly ethynylated mono and dinuclear Pt(II) tethers containing nitrogroups and organic models as redox active probes: X-ray crystal structure of trans-[Pt(CC-C6H4NO2) 2(PPh3)2]",

abstract = "The electrochemical study on Pt(II) organometallic and organic ethynylated compounds bearing nitro substituents in the phenyl groups has been performed, demonstrating that the presence of severe chemical irreversibility accompanying the electron transfer, preclude an evaluation of the electronic communication between redox active centres. The X-ray structure of the complex trans-[Pt(CC-C6H4NO2)2(PPh 3)2] is showed.",

keywords = "Cyclic voltammetry, Ethynylated compound, Pt(II), X-ray structure",

author = "Mauro Ravera and Rosaria D'Amato and Annalisa Guerri",

note = "Funding Information: The authors are grateful to MIUR (Ministero dell{\textquoteright}Istruzione, dell{\textquoteright}Universit{\`a} e della Ricerca) Italy (COFIN 2002) for the financial support to this research and to CRIST (Centro Interdipartimentale di Cristallografia Strutturale, Universit{\`a} di Firenze) where the X-ray measurement was carried out. ",

year = "2005",

month = apr,

day = "29",

doi = "10.1016/j.jorganchem.2005.02.014",

language = "English",

volume = "690",

pages = "2376--2380",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "9",

}

Probing delocalisation across highly ethynylated mono and dinuclear Pt(II) tethers containing nitrogroups and organic models as redox active probes: X-ray crystal structure of trans-[Pt(CC-C₆H₄NO₂) ₂(PPh₃)₂]. / Ravera, Mauro; D'Amato, Rosaria; Guerri, Annalisa.
In: Journal of Organometallic Chemistry, Vol. 690, N. 9, 29.04.2005, pag. 2376-2380.

Risultato della ricerca: Contributo su rivista › Breve indagine › peer review

TY - JOUR

T1 - Probing delocalisation across highly ethynylated mono and dinuclear Pt(II) tethers containing nitrogroups and organic models as redox active probes

T2 - X-ray crystal structure of trans-[Pt(CC-C6H4NO2) 2(PPh3)2]

AU - Ravera, Mauro

AU - D'Amato, Rosaria

AU - Guerri, Annalisa

N1 - Funding Information: The authors are grateful to MIUR (Ministero dell’Istruzione, dell’Università e della Ricerca) Italy (COFIN 2002) for the financial support to this research and to CRIST (Centro Interdipartimentale di Cristallografia Strutturale, Università di Firenze) where the X-ray measurement was carried out.

PY - 2005/4/29

Y1 - 2005/4/29

N2 - The electrochemical study on Pt(II) organometallic and organic ethynylated compounds bearing nitro substituents in the phenyl groups has been performed, demonstrating that the presence of severe chemical irreversibility accompanying the electron transfer, preclude an evaluation of the electronic communication between redox active centres. The X-ray structure of the complex trans-[Pt(CC-C6H4NO2)2(PPh 3)2] is showed.

AB - The electrochemical study on Pt(II) organometallic and organic ethynylated compounds bearing nitro substituents in the phenyl groups has been performed, demonstrating that the presence of severe chemical irreversibility accompanying the electron transfer, preclude an evaluation of the electronic communication between redox active centres. The X-ray structure of the complex trans-[Pt(CC-C6H4NO2)2(PPh 3)2] is showed.

KW - Cyclic voltammetry

KW - Ethynylated compound

KW - Pt(II)

KW - X-ray structure

U2 - 10.1016/j.jorganchem.2005.02.014

DO - 10.1016/j.jorganchem.2005.02.014

M3 - Short survey

SN - 0022-328X

VL - 690

SP - 2376

EP - 2380

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 9

ER -

Probing delocalisation across highly ethynylated mono and dinuclear Pt(II) tethers containing nitrogroups and organic models as redox active probes: X-ray crystal structure of trans-[Pt(CC-C6H4NO2) 2(PPh3)2]

Abstract

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Cita questo

Probing delocalisation across highly ethynylated mono and dinuclear Pt(II) tethers containing nitrogroups and organic models as redox active probes: X-ray crystal structure of trans-[Pt(CC-C₆H₄NO₂) ₂(PPh₃)₂]