Probing delocalisation across highly ethynylated mono and dinuclear Pt(II) tethers containing nitrogroups and organic models as redox active probes: X-ray crystal structure of trans-[Pt(CC-C6H4NO2) 2(PPh3)2]

Mauro Ravera, Rosaria D'Amato, Annalisa Guerri

Risultato della ricerca: Contributo su rivistaBreve indaginepeer review

Abstract

The electrochemical study on Pt(II) organometallic and organic ethynylated compounds bearing nitro substituents in the phenyl groups has been performed, demonstrating that the presence of severe chemical irreversibility accompanying the electron transfer, preclude an evaluation of the electronic communication between redox active centres. The X-ray structure of the complex trans-[Pt(CC-C6H4NO2)2(PPh 3)2] is showed.

Lingua originaleInglese
pagine (da-a)2376-2380
Numero di pagine5
RivistaJournal of Organometallic Chemistry
Volume690
Numero di pubblicazione9
DOI
Stato di pubblicazionePubblicato - 29 apr 2005

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