Polyoxygenated Eudesmanes and trans-Chrysanthemanes from the Aerial Parts of Santolina insularis

Ernesto Fattorusso; Federico U. Santelia; Giovanni Appendino; Mauro Ballero; Orazio Taglialatela-Scafati

doi:10.1021/np030222l

Polyoxygenated Eudesmanes and trans-Chrysanthemanes from the Aerial Parts of Santolina insularis

Ernesto Fattorusso, Federico U. Santelia, Giovanni Appendino, Mauro Ballero, Orazio Taglialatela-Scafati

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

The eudesmane sesquiterpenoids 1-3 and the trans-chrysanthemyl monoterpenoid 4 have been isolated from the aerial parts of Santolina insularis, a bush endemic to Sardinia. The absolute stereostructures of these novel compounds and of two known but incompletely characterized chrysanthemanes (5, 6) were established by spectroscopic techniques and by application of the modified Mosher method. The presence of the p-menthane aldehyde eucamalol (7) gives credit to the widespread use of S. insularis to fend off mosquitoes.

Lingua originale	Inglese
pagine (da-a)	37-41
Numero di pagine	5
Rivista	Journal of Natural Products
Volume	67
Numero di pubblicazione	1
DOI	https://doi.org/10.1021/np030222l
Stato di pubblicazione	Pubblicato - gen 2004
Pubblicato esternamente	Sì

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10.1021/np030222l

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abstract = "The eudesmane sesquiterpenoids 1-3 and the trans-chrysanthemyl monoterpenoid 4 have been isolated from the aerial parts of Santolina insularis, a bush endemic to Sardinia. The absolute stereostructures of these novel compounds and of two known but incompletely characterized chrysanthemanes (5, 6) were established by spectroscopic techniques and by application of the modified Mosher method. The presence of the p-menthane aldehyde eucamalol (7) gives credit to the widespread use of S. insularis to fend off mosquitoes.",

author = "Ernesto Fattorusso and Santelia, {Federico U.} and Giovanni Appendino and Mauro Ballero and Orazio Taglialatela-Scafati",

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AU - Ballero, Mauro

AU - Taglialatela-Scafati, Orazio

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AB - The eudesmane sesquiterpenoids 1-3 and the trans-chrysanthemyl monoterpenoid 4 have been isolated from the aerial parts of Santolina insularis, a bush endemic to Sardinia. The absolute stereostructures of these novel compounds and of two known but incompletely characterized chrysanthemanes (5, 6) were established by spectroscopic techniques and by application of the modified Mosher method. The presence of the p-menthane aldehyde eucamalol (7) gives credit to the widespread use of S. insularis to fend off mosquitoes.

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ER -

Polyoxygenated Eudesmanes and trans-Chrysanthemanes from the Aerial Parts of Santolina insularis

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