TY - JOUR
T1 - Oxygen-17 relaxation times of metallocarbonyls
T2 - The use of the 17O electric quadrupole coupling as a new structural probe
AU - Aime, Silvio
AU - Gobetto, Roberto
AU - Osella, Domenico
AU - Milone, Luciano
AU - Hawkes, Geoffrey E.
AU - Randall, Edward W.
PY - 1983
Y1 - 1983
N2 - The 17O spin-lattice relaxation times at 54.25 MHz for seven selected metallocarbonyls are in the range 8 to 50 ms at 298 K; the variations are dependent upon the molecular size, the transition metal, and the stereochemical position of the CO group, and may be interpreted in terms of variation of 17O electric quadrupole coupling constants which show stereochemical dependence, when the effects of correlation times have been allowed for.
AB - The 17O spin-lattice relaxation times at 54.25 MHz for seven selected metallocarbonyls are in the range 8 to 50 ms at 298 K; the variations are dependent upon the molecular size, the transition metal, and the stereochemical position of the CO group, and may be interpreted in terms of variation of 17O electric quadrupole coupling constants which show stereochemical dependence, when the effects of correlation times have been allowed for.
UR - http://www.scopus.com/inward/record.url?scp=37049106137&partnerID=8YFLogxK
U2 - 10.1039/c39830000794
DO - 10.1039/c39830000794
M3 - Article
SN - 0022-4936
SP - 794
EP - 796
JO - Chemical Communications
JF - Chemical Communications
IS - 15
ER -