Notes. Carbon-13 and oxygen-17 nuclear magnetic resonance relaxation studies of [M3(CO)12] derivatives (M = Fe, Ru, or Os)

Silvio Aime; Mauro Botta; Roberto Gobetto; Domenico Osella

doi:10.1039/DT9880000791

Notes. Carbon-13 and oxygen-17 nuclear magnetic resonance relaxation studies of [M₃(CO)₁₂] derivatives (M = Fe, Ru, or Os)

Silvio Aime, Mauro Botta, Roberto Gobetto, Domenico Osella

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

The combined use of ¹³C and ¹⁷O spin-lattice relaxation times for co-ordinated carbonyl ligands in [M₃(CO)₁₂] clusters (M = Fe, Ru, or Os) allows the determination of ¹⁷O quadrupolar coupling constants and the correlation times for molecular tumbling at different temperatures.

Lingua originale	Inglese
pagine (da-a)	791-792
Numero di pagine	2
Rivista	Journal of the Chemical Society. Dalton Transactions
Numero di pubblicazione	3
DOI	https://doi.org/10.1039/DT9880000791
Stato di pubblicazione	Pubblicato - 1988
Pubblicato esternamente	Sì

Accesso al documento

10.1039/DT9880000791

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title = "Notes. Carbon-13 and oxygen-17 nuclear magnetic resonance relaxation studies of [M3(CO)12] derivatives (M = Fe, Ru, or Os)",

abstract = "The combined use of 13C and 17O spin-lattice relaxation times for co-ordinated carbonyl ligands in [M3(CO)12] clusters (M = Fe, Ru, or Os) allows the determination of 17O quadrupolar coupling constants and the correlation times for molecular tumbling at different temperatures.",

author = "Silvio Aime and Mauro Botta and Roberto Gobetto and Domenico Osella",

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AU - Botta, Mauro

AU - Gobetto, Roberto

AU - Osella, Domenico

PY - 1988

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AB - The combined use of 13C and 17O spin-lattice relaxation times for co-ordinated carbonyl ligands in [M3(CO)12] clusters (M = Fe, Ru, or Os) allows the determination of 17O quadrupolar coupling constants and the correlation times for molecular tumbling at different temperatures.

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