TY - JOUR
T1 - NMR-STUDIES OF L-DOPA MELANIN-MANGANESE(II) COMPLEX IN WATER SOLUTION
AU - AIME, S
AU - BOTTA, Mauro
AU - CAMURATI, I.
PY - 1989
Y1 - 1989
N2 - The study of water relaxation rates of solutions of melanins with paramagnetic metal ions provides a powerful tool for investigating the binding sites and for obtaining useful structural and dynamic information. The measure of 1H- and 2H-longitudinal and transverse relaxation rates at a single, high-magnetic field for H2O/D2O(80:20) solutions allows the determination of τc, τR, τe, τM, r, q, and Z (the outer sphere contribution to the overall relaxation rate) for Mn(II)-L-Dopa melanin system.
AB - The study of water relaxation rates of solutions of melanins with paramagnetic metal ions provides a powerful tool for investigating the binding sites and for obtaining useful structural and dynamic information. The measure of 1H- and 2H-longitudinal and transverse relaxation rates at a single, high-magnetic field for H2O/D2O(80:20) solutions allows the determination of τc, τR, τe, τM, r, q, and Z (the outer sphere contribution to the overall relaxation rate) for Mn(II)-L-Dopa melanin system.
UR - https://iris.uniupo.it/handle/11579/648
U2 - 10.1016/0162-0134(89)80008-X
DO - 10.1016/0162-0134(89)80008-X
M3 - Article
SN - 0162-0134
VL - 36
SP - 1
EP - 9
JO - Journal of Inorganic Biochemistry
JF - Journal of Inorganic Biochemistry
IS - 1
ER -