Investigation of the electrochemical behavior and electronic structure of (M-butatriene)hexacarbonyldiiron complexes

Domenico Osella, Olimpia Gambino, Roberto Gobetto, Piero Zanello, Franco Laschi, Steven M. Owen, Catherine E. Housecroft

Risultato della ricerca: Contributo su rivistaArticolo in rivistapeer review

Abstract

The redox chemistry of (jt-butatriene)hexacarbonyldiiron compounds, Ρβ2(0Ο)6(ΜΙΌ=0=0=0ΙΙΙΙ’), has been investigated by electrochemical and spectroscopic methods and Fenske-Hall quantum-chemical calculations. The sequence of the electrode processes has been postulated on the basis of the response of different electrochemical techniques, electron spin resonance (ESR) spectroscopy, and chemical tests. The butatriene chain, interacting with the bimetallic Fe2(CO)6 framework in a multicentered σ/π fashion, is able to stabilize the electrogenerated anions.

Lingua originaleInglese
pagine (da-a)1792-1797
Numero di pagine6
RivistaOrganometallics
Volume9
Numero di pubblicazione6
DOI
Stato di pubblicazionePubblicato - 1990
Pubblicato esternamente

Fingerprint

Entra nei temi di ricerca di 'Investigation of the electrochemical behavior and electronic structure of (M-butatriene)hexacarbonyldiiron complexes'. Insieme formano una fingerprint unica.

Cita questo