Abstract
The ability to adroitly tailor acid-strength using specifically-engineered bimetallic nanoporous materials has been investigated with a view to exploiting their potential in solid-acid catalysed transformations. Further, it has been demonstrated that through site-specific interactions, extra-framework zinc ions can suitably modify the acidity of Brønsted acid sites, to stimulate diverse catalytic responses, when combined with isomorphously-substituted framework metal cations within porous architectures, for the Beckmann rearrangement of cyclohexanone oxime and in the isopropylation of benzene.
Lingua originale | Inglese |
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pagine (da-a) | 13288-13295 |
Numero di pagine | 8 |
Rivista | Physical Chemistry Chemical Physics |
Volume | 15 |
Numero di pubblicazione | 32 |
DOI | |
Stato di pubblicazione | Pubblicato - 28 ago 2013 |