Investigating site-specific interactions and probing their role in modifying the acid-strength in framework architectures

Matthew E. Potter, Danni Sun, Enrica Gianotti, Maela Manzoli, Robert Raja

Risultato della ricerca: Contributo su rivistaArticolo in rivistapeer review

Abstract

The ability to adroitly tailor acid-strength using specifically-engineered bimetallic nanoporous materials has been investigated with a view to exploiting their potential in solid-acid catalysed transformations. Further, it has been demonstrated that through site-specific interactions, extra-framework zinc ions can suitably modify the acidity of Brønsted acid sites, to stimulate diverse catalytic responses, when combined with isomorphously-substituted framework metal cations within porous architectures, for the Beckmann rearrangement of cyclohexanone oxime and in the isopropylation of benzene.

Lingua originaleInglese
pagine (da-a)13288-13295
Numero di pagine8
RivistaPhysical Chemistry Chemical Physics
Volume15
Numero di pubblicazione32
DOI
Stato di pubblicazionePubblicato - 28 ago 2013

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