Interpretation of the terminal ν(CO) spectra of some M5 transition metal carbonyl clusters

S. F.A. Kettle; E. Diana; R. Rossetti; R. Della Pergola; E. Boccaleri; P. L. Stanghellini

doi:10.1016/S0020-1693(02)01559-1

Interpretation of the terminal ν(CO) spectra of some M₅ transition metal carbonyl clusters

S. F.A. Kettle, E. Diana, R. Rossetti, R. Della Pergola, E. Boccaleri, P. L. Stanghellini

Dipartimento per lo Sviluppo Sostenibile e la Transizione Ecologica

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

The ν(CO) spectra of 31 M₅ transition metal carbonyl clusters are interpreted in terms of the spherical harmonic and tensor harmonic models. It seems that the former is that which is generally applicable but that the splittings of the (spherical) P mode are larger than had previously been considered indicative of this model. An explanation in terms of the cluster asymmetry is suggested.

Lingua originale	Inglese
pagine (da-a)	32-38
Numero di pagine	7
Rivista	Inorganica Chimica Acta
Volume	350
DOI	https://doi.org/10.1016/S0020-1693(02)01559-1
Stato di pubblicazione	Pubblicato - 4 lug 2003

Accesso al documento

10.1016/S0020-1693(02)01559-1

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abstract = "The ν(CO) spectra of 31 M5 transition metal carbonyl clusters are interpreted in terms of the spherical harmonic and tensor harmonic models. It seems that the former is that which is generally applicable but that the splittings of the (spherical) P mode are larger than had previously been considered indicative of this model. An explanation in terms of the cluster asymmetry is suggested.",

keywords = "Image dipole, Spherical harmonic model, Tensor harmonic model, Transition metal carbonyl clusters, Vibrational spectra",

author = "Kettle, {S. F.A.} and E. Diana and R. Rossetti and {Della Pergola}, R. and E. Boccaleri and Stanghellini, {P. L.}",

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AU - Kettle, S. F.A.

AU - Diana, E.

AU - Rossetti, R.

AU - Della Pergola, R.

AU - Boccaleri, E.

AU - Stanghellini, P. L.

PY - 2003/7/4

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AB - The ν(CO) spectra of 31 M5 transition metal carbonyl clusters are interpreted in terms of the spherical harmonic and tensor harmonic models. It seems that the former is that which is generally applicable but that the splittings of the (spherical) P mode are larger than had previously been considered indicative of this model. An explanation in terms of the cluster asymmetry is suggested.

KW - Image dipole

KW - Spherical harmonic model

KW - Tensor harmonic model

KW - Transition metal carbonyl clusters

KW - Vibrational spectra

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U2 - 10.1016/S0020-1693(02)01559-1

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VL - 350

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EP - 38

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta