Interpretation of the ν(CO) vibrational spectra of cluster compounds: tetrahedral anions [Fe2Ir2(CO)12]2-, [HFe2Ir2(CO)12]- and [FeIr3(CO)12]-

S. F.A. Kettle; E. Diana; P. L. Stanghellini; R. Della Pergola

doi:10.1016/S0020-1693(00)92311-9

Interpretation of the ν(CO) vibrational spectra of cluster compounds: tetrahedral anions [Fe₂Ir₂(CO)₁₂]^2-, [HFe₂Ir₂(CO)₁₂]^- and [FeIr₃(CO)₁₂]^-

S. F.A. Kettle, E. Diana, P. L. Stanghellini, R. Della Pergola

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

The analysis of the ν(CO) infrared and Raman spectra of the title compounds demonstrates the feasibility of using reliable force constant data from a model species in the interpretation of the vibrational spectra of another. This parameter transferability, similar to that used in the Extended Huckel method, should lead to a progress in understanding the vibrational CO spectra of more complex, low symmetry metal carbonyl cluster compounds.

Lingua originale	Inglese
pagine (da-a)	75-79
Numero di pagine	5
Rivista	Inorganica Chimica Acta
Volume	212
Numero di pubblicazione	1-2
DOI	https://doi.org/10.1016/S0020-1693(00)92311-9
Stato di pubblicazione	Pubblicato - ott 1993
Pubblicato esternamente	Sì

Accesso al documento

10.1016/S0020-1693(00)92311-9

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title = "Interpretation of the ν(CO) vibrational spectra of cluster compounds: tetrahedral anions [Fe2Ir2(CO)12]2-, [HFe2Ir2(CO)12]- and [FeIr3(CO)12]-",

abstract = "The analysis of the ν(CO) infrared and Raman spectra of the title compounds demonstrates the feasibility of using reliable force constant data from a model species in the interpretation of the vibrational spectra of another. This parameter transferability, similar to that used in the Extended Huckel method, should lead to a progress in understanding the vibrational CO spectra of more complex, low symmetry metal carbonyl cluster compounds.",

author = "Kettle, {S. F.A.} and E. Diana and Stanghellini, {P. L.} and Pergola, {R. Della}",

year = "1993",

month = oct,

doi = "10.1016/S0020-1693(00)92311-9",

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T1 - Interpretation of the ν(CO) vibrational spectra of cluster compounds

T2 - tetrahedral anions [Fe2Ir2(CO)12]2-, [HFe2Ir2(CO)12]- and [FeIr3(CO)12]-

AU - Kettle, S. F.A.

AU - Diana, E.

AU - Stanghellini, P. L.

AU - Pergola, R. Della

PY - 1993/10

Y1 - 1993/10

N2 - The analysis of the ν(CO) infrared and Raman spectra of the title compounds demonstrates the feasibility of using reliable force constant data from a model species in the interpretation of the vibrational spectra of another. This parameter transferability, similar to that used in the Extended Huckel method, should lead to a progress in understanding the vibrational CO spectra of more complex, low symmetry metal carbonyl cluster compounds.

AB - The analysis of the ν(CO) infrared and Raman spectra of the title compounds demonstrates the feasibility of using reliable force constant data from a model species in the interpretation of the vibrational spectra of another. This parameter transferability, similar to that used in the Extended Huckel method, should lead to a progress in understanding the vibrational CO spectra of more complex, low symmetry metal carbonyl cluster compounds.

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U2 - 10.1016/S0020-1693(00)92311-9

DO - 10.1016/S0020-1693(00)92311-9

M3 - Article

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VL - 212

SP - 75

EP - 79

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

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