Improving the mesomorphic behaviour of supramolecular liquid crystals by resonance-assisted hydrogen bonding

Marco Saccone; Michael Pfletscher; Sven Kather; Christoph Wölper; Constantin Daniliuc; Markus Mezger; Michael Giese

doi:10.1039/c9tc02787d

Improving the mesomorphic behaviour of supramolecular liquid crystals by resonance-assisted hydrogen bonding

Marco Saccone
, Michael Pfletscher
, Sven Kather
, Christoph Wölper
, Constantin Daniliuc
, Markus Mezger
, Michael Giese

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

A systematic structure-property relationship study on hydrogen-bonded liquid crystals was performed, revealing the impact of resonance-assisted hydrogen bonds (RAHBs) on the self-assembling behavior of the supramolecular architecture. The creation of a six-membered intramolecular hydrogen-bonded ring acts as a counterpart to the self-organization between hydrogen bond donators and acceptors and determines thus the suprastructure. Variation of the hydrogen-bonding pattern allowed us to significantly improve the temperature range of the reported liquid crystalline assemblies.

Lingua originale	Inglese
pagine (da-a)	8643-8648
Numero di pagine	6
Rivista	Journal of Materials Chemistry C
Volume	7
Numero di pubblicazione	28
DOI	https://doi.org/10.1039/c9tc02787d
Stato di pubblicazione	Pubblicato - 2019
Pubblicato esternamente	Sì

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10.1039/c9tc02787d

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abstract = "A systematic structure-property relationship study on hydrogen-bonded liquid crystals was performed, revealing the impact of resonance-assisted hydrogen bonds (RAHBs) on the self-assembling behavior of the supramolecular architecture. The creation of a six-membered intramolecular hydrogen-bonded ring acts as a counterpart to the self-organization between hydrogen bond donators and acceptors and determines thus the suprastructure. Variation of the hydrogen-bonding pattern allowed us to significantly improve the temperature range of the reported liquid crystalline assemblies.",

author = "Marco Saccone and Michael Pfletscher and Sven Kather and Christoph W{\"o}lper and Constantin Daniliuc and Markus Mezger and Michael Giese",

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doi = "10.1039/c9tc02787d",

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AU - Saccone, Marco

AU - Pfletscher, Michael

AU - Kather, Sven

AU - Wölper, Christoph

AU - Daniliuc, Constantin

AU - Mezger, Markus

AU - Giese, Michael

PY - 2019

Y1 - 2019

N2 - A systematic structure-property relationship study on hydrogen-bonded liquid crystals was performed, revealing the impact of resonance-assisted hydrogen bonds (RAHBs) on the self-assembling behavior of the supramolecular architecture. The creation of a six-membered intramolecular hydrogen-bonded ring acts as a counterpart to the self-organization between hydrogen bond donators and acceptors and determines thus the suprastructure. Variation of the hydrogen-bonding pattern allowed us to significantly improve the temperature range of the reported liquid crystalline assemblies.

AB - A systematic structure-property relationship study on hydrogen-bonded liquid crystals was performed, revealing the impact of resonance-assisted hydrogen bonds (RAHBs) on the self-assembling behavior of the supramolecular architecture. The creation of a six-membered intramolecular hydrogen-bonded ring acts as a counterpart to the self-organization between hydrogen bond donators and acceptors and determines thus the suprastructure. Variation of the hydrogen-bonding pattern allowed us to significantly improve the temperature range of the reported liquid crystalline assemblies.

UR - https://www.scopus.com/pages/publications/85069527714

U2 - 10.1039/c9tc02787d

DO - 10.1039/c9tc02787d

M3 - Article

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VL - 7

SP - 8643

EP - 8648

JO - Journal of Materials Chemistry C

JF - Journal of Materials Chemistry C

IS - 28

ER -

Improving the mesomorphic behaviour of supramolecular liquid crystals by resonance-assisted hydrogen bonding

Abstract

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