Hetero-dinuclear sodium-lanthanide(III) complexes with an asymmetric compartmental macrocycle

Umberto Casellato; Sergio Tamburini; Patrizia Tomasin; Pietro A. Vigato; Silvio Aime; Alessandro Barge; Mauro Botta

doi:10.1039/a909367b

Hetero-dinuclear sodium-lanthanide(III) complexes with an asymmetric compartmental macrocycle

Umberto Casellato, Sergio Tamburini, Patrizia Tomasin, Pietro A. Vigato, Silvio Aime, Alessandro Barge, Mauro Botta

Dipartimento di Scienze e Innovazione Tecnologica

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

A heterodinuclear macrocyclic complex containing both Yb³⁺ and Na⁺ ions has been synthesized and characterized by X-ray crystallography and ¹H and ²³Na solution NMR; at room temperature the coordinated Na⁺ ion is in slow chemical exchange with free Na⁺ ions and its NMR resonance is strongly shifted.

Lingua originale	Inglese
pagine (da-a)	145-146
Numero di pagine	2
Rivista	Chemical Communications
Numero di pubblicazione	2
DOI	https://doi.org/10.1039/a909367b
Stato di pubblicazione	Pubblicato - 21 gen 2000

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10.1039/a909367b

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title = "Hetero-dinuclear sodium-lanthanide(III) complexes with an asymmetric compartmental macrocycle",

abstract = "A heterodinuclear macrocyclic complex containing both Yb3+ and Na+ ions has been synthesized and characterized by X-ray crystallography and 1H and 23Na solution NMR; at room temperature the coordinated Na+ ion is in slow chemical exchange with free Na+ ions and its NMR resonance is strongly shifted.",

author = "Umberto Casellato and Sergio Tamburini and Patrizia Tomasin and Vigato, {Pietro A.} and Silvio Aime and Alessandro Barge and Mauro Botta",

year = "2000",

month = jan,

day = "21",

doi = "10.1039/a909367b",

language = "English",

pages = "145--146",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Hetero-dinuclear sodium-lanthanide(III) complexes with an asymmetric compartmental macrocycle

AU - Casellato, Umberto

AU - Tamburini, Sergio

AU - Tomasin, Patrizia

AU - Vigato, Pietro A.

AU - Aime, Silvio

AU - Barge, Alessandro

AU - Botta, Mauro

PY - 2000/1/21

Y1 - 2000/1/21

N2 - A heterodinuclear macrocyclic complex containing both Yb3+ and Na+ ions has been synthesized and characterized by X-ray crystallography and 1H and 23Na solution NMR; at room temperature the coordinated Na+ ion is in slow chemical exchange with free Na+ ions and its NMR resonance is strongly shifted.

AB - A heterodinuclear macrocyclic complex containing both Yb3+ and Na+ ions has been synthesized and characterized by X-ray crystallography and 1H and 23Na solution NMR; at room temperature the coordinated Na+ ion is in slow chemical exchange with free Na+ ions and its NMR resonance is strongly shifted.

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U2 - 10.1039/a909367b

DO - 10.1039/a909367b

M3 - Article

SN - 1359-7345

SP - 145

EP - 146

JO - Chemical Communications

JF - Chemical Communications

IS - 2

ER -

Hetero-dinuclear sodium-lanthanide(III) complexes with an asymmetric compartmental macrocycle

Abstract

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