@article{c3a47ac09761466f81d1b0ea30627de3,
title = "Experimental and computational investigations on the AlH 3/AlF3 system",
abstract = "The possibility of changing the thermodynamic properties of AlH 3, alane, by fluorine anion substitution has been investigated by experimental measurements, ab initio calculations and thermodynamic modelling. No solid solution phases are observed experimentally. In accordance to this the calculations give a positive free energy of mixing for all compositions, showing that a mixed phase is not thermodynamically favourable. Thus fluorine anion substitution does not seem feasible for the alane system.",
keywords = "Energy storage materials, Mechanochemical synthesis, Metal hydrides, Phase diagrams, Thermodynamic modelling, Thermodynamic properties",
author = "Fonnel{\o}p, {Jon Erling} and Marta Corno and Hilde Grove and Eugenio Pinatel and S{\o}rby, {Magnus H.} and Piero Ugliengo and Marcello Baricco and Hauback, {Bj{\o}rn C.}",
note = "Funding Information: This work was supported from the FLYHY project (contract no. 226943 ) under the FP7 Program in the European Commission and by the RENERGI program of the Research Council of Norway . The skilful assistance of the project team at the Swiss-Norwegian beam line (ESRF) is gratefully acknowledged. Fluorsid is acknowledged for providing single phase AlF 3 .",
year = "2011",
month = jan,
day = "5",
doi = "10.1016/j.jallcom.2010.08.147",
language = "English",
volume = "509",
pages = "10--14",
journal = "Journal of Alloys and Compounds",
issn = "0925-8388",
publisher = "Elsevier B.V.",
number = "1",
}