Enhancement of the luminescence properties of eu (Iii) containing paramagnetic saponite clays

Stefano Marchesi, Chiara Bisio, Fabio Carniato

Risultato della ricerca: Contributo su rivistaArticolo in rivistapeer review

Abstract

In this study, 1,10-phenanthroline molecules were introduced in the interlayer space of a paramagnetic synthetic saponite clay containing both Eu3+ and Gd3+ ions in structural positions. Two samples with different loading of phenanthroline dye were prepared. The resulting hybrid materials possessed improved optical emission properties due to an efficient antenna effect from the phenanthroline to the Eu3+ centers; this effect was demonstrated to be higher than the metal-to-metal Gd3+-Eu3+ energy transfer previously studied. Insights on the relaxometric properties in aqueous solution of the solids after incorporation of the antenna groups were also obtained through NMR relaxometric analyses.

Lingua originaleInglese
Numero di articolo8903
RivistaApplied Sciences (Switzerland)
Volume11
Numero di pubblicazione19
DOI
Stato di pubblicazionePubblicato - 1 ott 2021

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