Electronic structure of some methinyltricobalt enneacarbonyls by means of ultraviolet photoelectron spectroscopy

Gaetano Granozzi; Sergio Agnolin; Maurizio Casarin; Domenico Osella

doi:10.1016/S0022-328X(00)89184-6

Electronic structure of some methinyltricobalt enneacarbonyls by means of ultraviolet photoelectron spectroscopy

Gaetano Granozzi, Sergio Agnolin, Maurizio Casarin, Domenico Osella

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

The He(I) excited photoelectron spectra of Co₃(CO)₉CY (where Y CH₃, F, Cl) are presented, and assignments of the bands to the ionization events are made on the basis of qualitative arguments. The photoelectron data agree with the representation of this cluster as an electron sink capable of π-interaction with the substituent Y.

Lingua originale	Inglese
pagine (da-a)	C6-C8
Rivista	Journal of Organometallic Chemistry
Volume	208
Numero di pubblicazione	1
DOI	https://doi.org/10.1016/S0022-328X(00)89184-6
Stato di pubblicazione	Pubblicato - 17 mar 1981
Pubblicato esternamente	Sì

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10.1016/S0022-328X(00)89184-6

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title = "Electronic structure of some methinyltricobalt enneacarbonyls by means of ultraviolet photoelectron spectroscopy",

abstract = "The He(I) excited photoelectron spectra of Co3(CO)9CY (where Y CH3, F, Cl) are presented, and assignments of the bands to the ionization events are made on the basis of qualitative arguments. The photoelectron data agree with the representation of this cluster as an electron sink capable of π-interaction with the substituent Y.",

author = "Gaetano Granozzi and Sergio Agnolin and Maurizio Casarin and Domenico Osella",

year = "1981",

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T1 - Electronic structure of some methinyltricobalt enneacarbonyls by means of ultraviolet photoelectron spectroscopy

AU - Granozzi, Gaetano

AU - Agnolin, Sergio

AU - Casarin, Maurizio

AU - Osella, Domenico

PY - 1981/3/17

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N2 - The He(I) excited photoelectron spectra of Co3(CO)9CY (where Y CH3, F, Cl) are presented, and assignments of the bands to the ionization events are made on the basis of qualitative arguments. The photoelectron data agree with the representation of this cluster as an electron sink capable of π-interaction with the substituent Y.

AB - The He(I) excited photoelectron spectra of Co3(CO)9CY (where Y CH3, F, Cl) are presented, and assignments of the bands to the ionization events are made on the basis of qualitative arguments. The photoelectron data agree with the representation of this cluster as an electron sink capable of π-interaction with the substituent Y.

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SP - C6-C8

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

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ER -

Electronic structure of some methinyltricobalt enneacarbonyls by means of ultraviolet photoelectron spectroscopy

Abstract

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