Electronic Interactions in Diyne Co2(CO)6 Complexes

N Duffy; J McAdam; C Nervi; Domenico OSELLA; Mauro RAVERA; B Robinson; J. Simpson

doi:10.1016/0020-1693(95)04949-5

Electronic Interactions in Diyne Co2(CO)6 Complexes

N Duffy
, J McAdam
, C Nervi
, Domenico OSELLA
, Mauro RAVERA
, B Robinson
, J. Simpson

Dipartimento di Scienze e Innovazione Tecnologica

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

Electrochemical criteria are used to evaluate the electronic interaction between redox centres in the π-conjugated diyne complexes (RCSC[Co₂(CO)₆]C=EC[Co₂(CO)₆]R] and (RC=C[Co₂(CO)₆]-(S)-C=C[Co₂(CO)₆]R] (R = Ph,Fc) where the aromatic spacer S is phenyl, napthalene or anthracene. Voltammetry at microelectrode, differential pulse techniques and low temperature measurements are used to obviate the chemical complications following the primary redox process. A mechanism is proposed which successfully simulates the electrochemical data.

Lingua originale	Inglese
pagine (da-a)	99-104
Numero di pagine	6
Rivista	Inorganica Chimica Acta
Volume	247
Numero di pubblicazione	1
DOI	https://doi.org/10.1016/0020-1693(95)04949-5
Stato di pubblicazione	Pubblicato - 1996

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10.1016/0020-1693(95)04949-5

http://hdl.handle.net/11579/31599

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@article{332e099d383e4db4b056916b68450627,

title = "Electronic Interactions in Diyne Co2(CO)6 Complexes",

abstract = "Electrochemical criteria are used to evaluate the electronic interaction between redox centres in the π-conjugated diyne complexes (RCSC[Co2(CO)6]C=EC[Co2(CO)6]R] and (RC=C[Co2(CO)6]-(S)-C=C[Co2(CO)6]R] (R = Ph,Fc) where the aromatic spacer S is phenyl, napthalene or anthracene. Voltammetry at microelectrode, differential pulse techniques and low temperature measurements are used to obviate the chemical complications following the primary redox process. A mechanism is proposed which successfully simulates the electrochemical data.",

author = "N Duffy and J McAdam and C Nervi and Domenico OSELLA and Mauro RAVERA and B Robinson and J. Simpson",

note = "Funding Information: D.O is indebtetdo t heE uropeanU nionf ora fellowshipa t theH eyrovskIyn stitute(P ragueC, zechR epublic)w ithint he PECO programmeT.h e Otago group acknowledgetsh e award of a Travel Grant undert he NZ/NSF Scientific Exchangep rogrammteo enablet he ESR work at Brown UniversityR, hodeIs land,a ndt hankP rofessoPr . Riegerf or theu seo f his instrumentatiaonnd h is interesat nda dvicein thew ork.",

year = "1996",

doi = "10.1016/0020-1693(95)04949-5",

language = "English",

volume = "247",

pages = "99--104",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

number = "1",

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TY - JOUR

T1 - Electronic Interactions in Diyne Co2(CO)6 Complexes

AU - Duffy, N

AU - McAdam, J

AU - Nervi, C

AU - OSELLA, Domenico

AU - RAVERA, Mauro

AU - Robinson, B

AU - Simpson, J.

N1 - Funding Information: D.O is indebtetdo t heE uropeanU nionf ora fellowshipa t theH eyrovskIyn stitute(P ragueC, zechR epublic)w ithint he PECO programmeT.h e Otago group acknowledgetsh e award of a Travel Grant undert he NZ/NSF Scientific Exchangep rogrammteo enablet he ESR work at Brown UniversityR, hodeIs land,a ndt hankP rofessoPr . Riegerf or theu seo f his instrumentatiaonnd h is interesat nda dvicein thew ork.

PY - 1996

Y1 - 1996

N2 - Electrochemical criteria are used to evaluate the electronic interaction between redox centres in the π-conjugated diyne complexes (RCSC[Co2(CO)6]C=EC[Co2(CO)6]R] and (RC=C[Co2(CO)6]-(S)-C=C[Co2(CO)6]R] (R = Ph,Fc) where the aromatic spacer S is phenyl, napthalene or anthracene. Voltammetry at microelectrode, differential pulse techniques and low temperature measurements are used to obviate the chemical complications following the primary redox process. A mechanism is proposed which successfully simulates the electrochemical data.

AB - Electrochemical criteria are used to evaluate the electronic interaction between redox centres in the π-conjugated diyne complexes (RCSC[Co2(CO)6]C=EC[Co2(CO)6]R] and (RC=C[Co2(CO)6]-(S)-C=C[Co2(CO)6]R] (R = Ph,Fc) where the aromatic spacer S is phenyl, napthalene or anthracene. Voltammetry at microelectrode, differential pulse techniques and low temperature measurements are used to obviate the chemical complications following the primary redox process. A mechanism is proposed which successfully simulates the electrochemical data.

UR - https://iris.uniupo.it/handle/11579/31599

U2 - 10.1016/0020-1693(95)04949-5

DO - 10.1016/0020-1693(95)04949-5

M3 - Article

SN - 0020-1693

VL - 247

SP - 99

EP - 104

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -

Electronic Interactions in Diyne Co2(CO)6 Complexes

Abstract

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