@article{332e099d383e4db4b056916b68450627,
title = "Electronic interactions in diyne Co2(CO)6 complexes",
abstract = "Electrochemical criteria are used to evaluate the electronic interaction between redox centres in the π-conjugated diyne complexes (RCSC[Co2(CO)6]C=EC[Co2(CO)6]R] and (RC=C[Co2(CO)6]-(S)-C=C[Co2(CO)6]R] (R = Ph,Fc) where the aromatic spacer S is phenyl, napthalene or anthracene. Voltammetry at microelectrode, differential pulse techniques and low temperature measurements are used to obviate the chemical complications following the primary redox process. A mechanism is proposed which successfully simulates the electrochemical data.",
keywords = "Carbonyl complexes, Cobalt complexes, Diyne complexes, Electrochemistry",
author = "Noel Duffy and John McAdam and Carlo Nervi and Domenico Osella and Mauro Ravera and Brian Robinson and Jim Simpson",
note = "Funding Information: D.O is indebtetdo t heE uropeanU nionf ora fellowshipa t theH eyrovskIyn stitute(P ragueC, zechR epublic)w ithint he PECO programmeT.h e Otago group acknowledgetsh e award of a Travel Grant undert he NZ/NSF Scientific Exchangep rogrammteo enablet he ESR work at Brown UniversityR, hodeIs land,a ndt hankP rofessoPr . Riegerf or theu seo f his instrumentatiaonnd h is interesat nda dvicein thew ork.",
year = "1996",
month = jun,
day = "15",
doi = "10.1016/0020-1693(95)04949-5",
language = "English",
volume = "247",
pages = "99--104",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier B.V.",
number = "1",
}