Electrochemical Behavior of the Electronically and Coordinatively Unsaturated [Os3(µ-H)(CO)8{Ph2PCH2P(Ph)C6H4}] Cluster

Domenico OSELLA, Mauro RAVERA, A. K. SMITH, A. J. MATHEWS, P. ZANELLO

Risultato della ricerca: Contributo su rivistaArticolo in rivistapeer review

Abstract

The electrochemical behaviour of the unsaturated cluster Os3(H)(CO)8[Ph2PCH2P(Ph)C6H4] has been studied by electrochemical and spectroscopic methods. The transformations of the very reactive title compound into the saturated cluster Os3(H)(CO)9[Ph2PCH2P(Ph)C6H4] and Os3(CO)10(Ph2PCH2PPh2] by CO addition has been followed step-by-step by cyclic voltammetry.

Lingua originaleInglese
pagine (da-a)255-261
Numero di pagine7
RivistaJournal of Organometallic Chemistry
Volume423
DOI
Stato di pubblicazionePubblicato - 1992

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