Dehydrative glycosylation with the Hendrickson reagent

M MOSSOTTI; Luigi PANZA

Dehydrative glycosylation with the Hendrickson reagent

M MOSSOTTI
, Luigi PANZA

Dipartimento di Scienze del Farmaco

Risultato della ricerca: Contributo su rivista › Articolo in rivista

Abstract

The Hendrickson reagent is able to perform efficiently dehydrative glycosylation of 1-hydroxyglycosyl donors. The reaction occurs under mild conditions through an anomeric oxophosphonium intermediate detected by nuclear magnetic resonance. Further insight into the mechanism was gained by ¹⁸O labeling of anomeric OH.

Lingua originale	Inglese
pagine (da-a)	9122-9126
Numero di pagine	5
Rivista	Journal of Organic Chemistry
Volume	76
Stato di pubblicazione	Pubblicato - 2011

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http://hdl.handle.net/11579/15651

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title = "Dehydrative glycosylation with the Hendrickson reagent",

abstract = "The Hendrickson reagent is able to perform efficiently dehydrative glycosylation of 1-hydroxyglycosyl donors. The reaction occurs under mild conditions through an anomeric oxophosphonium intermediate detected by nuclear magnetic resonance. Further insight into the mechanism was gained by 18O labeling of anomeric OH.",

author = "M MOSSOTTI and Luigi PANZA",

year = "2011",

language = "English",

volume = "76",

pages = "9122--9126",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

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T1 - Dehydrative glycosylation with the Hendrickson reagent

AU - MOSSOTTI, M

AU - PANZA, Luigi

PY - 2011

Y1 - 2011

N2 - The Hendrickson reagent is able to perform efficiently dehydrative glycosylation of 1-hydroxyglycosyl donors. The reaction occurs under mild conditions through an anomeric oxophosphonium intermediate detected by nuclear magnetic resonance. Further insight into the mechanism was gained by 18O labeling of anomeric OH.

AB - The Hendrickson reagent is able to perform efficiently dehydrative glycosylation of 1-hydroxyglycosyl donors. The reaction occurs under mild conditions through an anomeric oxophosphonium intermediate detected by nuclear magnetic resonance. Further insight into the mechanism was gained by 18O labeling of anomeric OH.

UR - https://iris.uniupo.it/handle/11579/15651

M3 - Article

SN - 0022-3263

VL - 76

SP - 9122

EP - 9126

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

ER -

Dehydrative glycosylation with the Hendrickson reagent

Abstract

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