Abstract
The Hendrickson reagent is able to perform efficiently dehydrative glycosylation of 1-hydroxyglycosyl donors. The reaction occurs under mild conditions through an anomeric oxophosphonium intermediate detected by nuclear magnetic resonance. Further insight into the mechanism was gained by 18O labeling of anomeric OH.
Lingua originale | Inglese |
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pagine (da-a) | 9122-9126 |
Numero di pagine | 5 |
Rivista | Journal of Organic Chemistry |
Volume | 76 |
Numero di pubblicazione | 21 |
DOI | |
Stato di pubblicazione | Pubblicato - 4 nov 2011 |