Dehydrative alkylation of alcohols with triethyl methanetricarboxylate under Mitsunobu conditions

Giancarlo Cravotto; Giovanni B. Giovenzana; Massimo Sisti; Giovanni Palmisano

doi:10.1016/0040-4020(96)00781-8

Dehydrative alkylation of alcohols with triethyl methanetricarboxylate under Mitsunobu conditions

Giancarlo Cravotto, Giovanni B. Giovenzana, Massimo Sisti, Giovanni Palmisano

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

Triethyl methanetricarboxylate (TEMT) can be mildly alkylated by primary, benzylic and allylic alcohols under classical Mitsunobu conditions, in fair to good yields. The utility of TEMT in organic synthesis as a diethyl malonate surrogate is reported.

Lingua originale	Inglese
pagine (da-a)	13007-13016
Numero di pagine	10
Rivista	Tetrahedron
Volume	52
Numero di pubblicazione	40
DOI	https://doi.org/10.1016/0040-4020(96)00781-8
Stato di pubblicazione	Pubblicato - 30 set 1996
Pubblicato esternamente	Sì

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10.1016/0040-4020(96)00781-8

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title = "Dehydrative alkylation of alcohols with triethyl methanetricarboxylate under Mitsunobu conditions",

abstract = "Triethyl methanetricarboxylate (TEMT) can be mildly alkylated by primary, benzylic and allylic alcohols under classical Mitsunobu conditions, in fair to good yields. The utility of TEMT in organic synthesis as a diethyl malonate surrogate is reported.",

author = "Giancarlo Cravotto and Giovenzana, {Giovanni B.} and Massimo Sisti and Giovanni Palmisano",

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AU - Cravotto, Giancarlo

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AU - Sisti, Massimo

AU - Palmisano, Giovanni

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AB - Triethyl methanetricarboxylate (TEMT) can be mildly alkylated by primary, benzylic and allylic alcohols under classical Mitsunobu conditions, in fair to good yields. The utility of TEMT in organic synthesis as a diethyl malonate surrogate is reported.

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DO - 10.1016/0040-4020(96)00781-8

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JO - Tetrahedron

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Dehydrative alkylation of alcohols with triethyl methanetricarboxylate under Mitsunobu conditions

Abstract

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