Coordination networks incorporating halogen-bond donor sites and azobenzene groups

Francisco Fernandez-Palacio; Marco Saccone; Arri Priimagi; Giancarlo Terraneo; Tullio Pilati; Pierangelo Metrangolo; Giuseppe Resnati

doi:10.1039/c6ce00059b

Coordination networks incorporating halogen-bond donor sites and azobenzene groups

Francisco Fernandez-Palacio, Marco Saccone, Arri Priimagi, Giancarlo Terraneo, Tullio Pilati, Pierangelo Metrangolo, Giuseppe Resnati

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

Two Zn coordination networks, {[Zn(1)(Py)₂]₂(2-propanol)}_n (3) and {[Zn(1)₂(Bipy)₂](DMF)₂}_n (4), incorporating halogen-bond (XB) donor sites and azobenzene groups have been synthesized and fully characterized. Obtaining 3 and 4 confirms that it is possible to use a ligand wherein its coordination bond acceptor sites and XB donor sites are on the same molecular scaffold (i.e., an aromatic ring) without interfering with each other. We demonstrate that XBs play a fundamental role in the architectures and properties of the obtained coordination networks. In 3, XBs promote the formation of 2D supramolecular layers, which, by overlapping each other, allow the incorporation of 2-propanol as a guest molecule. In 4, XBs support the connection of the layers and are essential to firmly pin DMF solvent molecules through I⋯O contacts, thus increasing the stability of the solvated systems.

Lingua originale	Inglese
pagine (da-a)	2251-2257
Numero di pagine	7
Rivista	CrystEngComm
Volume	18
Numero di pubblicazione	13
DOI	https://doi.org/10.1039/c6ce00059b
Stato di pubblicazione	Pubblicato - 7 apr 2016
Pubblicato esternamente	Sì

Accesso al documento

10.1039/c6ce00059b

Altri file e collegamenti

Link to publication in Scopus

Cita questo

@article{69555d70fae5405da132c11ff2cfdded,

title = "Coordination networks incorporating halogen-bond donor sites and azobenzene groups",

abstract = "Two Zn coordination networks, \{[Zn(1)(Py)2]2(2-propanol)\}n (3) and \{[Zn(1)2(Bipy)2](DMF)2\}n (4), incorporating halogen-bond (XB) donor sites and azobenzene groups have been synthesized and fully characterized. Obtaining 3 and 4 confirms that it is possible to use a ligand wherein its coordination bond acceptor sites and XB donor sites are on the same molecular scaffold (i.e., an aromatic ring) without interfering with each other. We demonstrate that XBs play a fundamental role in the architectures and properties of the obtained coordination networks. In 3, XBs promote the formation of 2D supramolecular layers, which, by overlapping each other, allow the incorporation of 2-propanol as a guest molecule. In 4, XBs support the connection of the layers and are essential to firmly pin DMF solvent molecules through I⋯O contacts, thus increasing the stability of the solvated systems.",

author = "Francisco Fernandez-Palacio and Marco Saccone and Arri Priimagi and Giancarlo Terraneo and Tullio Pilati and Pierangelo Metrangolo and Giuseppe Resnati",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

month = apr,

day = "7",

doi = "10.1039/c6ce00059b",

language = "English",

volume = "18",

pages = "2251--2257",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "13",

}

TY - JOUR

T1 - Coordination networks incorporating halogen-bond donor sites and azobenzene groups

AU - Fernandez-Palacio, Francisco

AU - Saccone, Marco

AU - Priimagi, Arri

AU - Terraneo, Giancarlo

AU - Pilati, Tullio

AU - Metrangolo, Pierangelo

AU - Resnati, Giuseppe

PY - 2016/4/7

Y1 - 2016/4/7

N2 - Two Zn coordination networks, {[Zn(1)(Py)2]2(2-propanol)}n (3) and {[Zn(1)2(Bipy)2](DMF)2}n (4), incorporating halogen-bond (XB) donor sites and azobenzene groups have been synthesized and fully characterized. Obtaining 3 and 4 confirms that it is possible to use a ligand wherein its coordination bond acceptor sites and XB donor sites are on the same molecular scaffold (i.e., an aromatic ring) without interfering with each other. We demonstrate that XBs play a fundamental role in the architectures and properties of the obtained coordination networks. In 3, XBs promote the formation of 2D supramolecular layers, which, by overlapping each other, allow the incorporation of 2-propanol as a guest molecule. In 4, XBs support the connection of the layers and are essential to firmly pin DMF solvent molecules through I⋯O contacts, thus increasing the stability of the solvated systems.

AB - Two Zn coordination networks, {[Zn(1)(Py)2]2(2-propanol)}n (3) and {[Zn(1)2(Bipy)2](DMF)2}n (4), incorporating halogen-bond (XB) donor sites and azobenzene groups have been synthesized and fully characterized. Obtaining 3 and 4 confirms that it is possible to use a ligand wherein its coordination bond acceptor sites and XB donor sites are on the same molecular scaffold (i.e., an aromatic ring) without interfering with each other. We demonstrate that XBs play a fundamental role in the architectures and properties of the obtained coordination networks. In 3, XBs promote the formation of 2D supramolecular layers, which, by overlapping each other, allow the incorporation of 2-propanol as a guest molecule. In 4, XBs support the connection of the layers and are essential to firmly pin DMF solvent molecules through I⋯O contacts, thus increasing the stability of the solvated systems.

UR - https://www.scopus.com/pages/publications/84962331348

U2 - 10.1039/c6ce00059b

DO - 10.1039/c6ce00059b

M3 - Article

SN - 1466-8033

VL - 18

SP - 2251

EP - 2257

JO - CrystEngComm

JF - CrystEngComm

IS - 13

ER -

Coordination networks incorporating halogen-bond donor sites and azobenzene groups

Abstract

Accesso al documento

Altri file e collegamenti

Fingerprint

Cita questo