Conjugate addition of alkyl- and vinyl-copper complexes to α,β-unsaturated phosphonic esters. Stereospecific syntheses of γ,δ-unsaturated phosphonates

Francesco Nicotra; Luigi Panza; Giovanni Russo

doi:10.1039/C39840000005

Conjugate addition of alkyl- and vinyl-copper complexes to α,β-unsaturated phosphonic esters. Stereospecific syntheses of γ,δ-unsaturated phosphonates

Francesco Nicotra
, Luigi Panza
, Giovanni Russo

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

Alkylcopper complexes add to diethyl ethenylphosphonate to afford phosphonic esters with the alkyl chain increased by two carbon atoms; analogously vinylcopper complexes afford γ,δ-unsaturated phosphonic esters with retention of configuration in the double bond.

Lingua originale	Inglese
pagine (da-a)	5-6
Numero di pagine	2
Rivista	Chemical Communications
Numero di pubblicazione	1
DOI	https://doi.org/10.1039/C39840000005
Stato di pubblicazione	Pubblicato - 1984
Pubblicato esternamente	Sì

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10.1039/C39840000005

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@article{18240b8cb2b24e1fa3a4ec8ae9dc506b,

title = "Conjugate addition of alkyl- and vinyl-copper complexes to α,β-unsaturated phosphonic esters. Stereospecific syntheses of γ,δ-unsaturated phosphonates",

abstract = "Alkylcopper complexes add to diethyl ethenylphosphonate to afford phosphonic esters with the alkyl chain increased by two carbon atoms; analogously vinylcopper complexes afford γ,δ-unsaturated phosphonic esters with retention of configuration in the double bond.",

author = "Francesco Nicotra and Luigi Panza and Giovanni Russo",

year = "1984",

doi = "10.1039/C39840000005",

language = "English",

pages = "5--6",

journal = "Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "1",

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T1 - Conjugate addition of alkyl- and vinyl-copper complexes to α,β-unsaturated phosphonic esters. Stereospecific syntheses of γ,δ-unsaturated phosphonates

AU - Nicotra, Francesco

AU - Panza, Luigi

AU - Russo, Giovanni

PY - 1984

Y1 - 1984

N2 - Alkylcopper complexes add to diethyl ethenylphosphonate to afford phosphonic esters with the alkyl chain increased by two carbon atoms; analogously vinylcopper complexes afford γ,δ-unsaturated phosphonic esters with retention of configuration in the double bond.

AB - Alkylcopper complexes add to diethyl ethenylphosphonate to afford phosphonic esters with the alkyl chain increased by two carbon atoms; analogously vinylcopper complexes afford γ,δ-unsaturated phosphonic esters with retention of configuration in the double bond.

UR - https://www.scopus.com/pages/publications/37049111171

U2 - 10.1039/C39840000005

DO - 10.1039/C39840000005

M3 - Article

SN - 0022-4936

SP - 5

EP - 6

JO - Chemical Communications

JF - Chemical Communications

IS - 1

ER -

Conjugate addition of alkyl- and vinyl-copper complexes to α,β-unsaturated phosphonic esters. Stereospecific syntheses of γ,δ-unsaturated phosphonates

Abstract

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